trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide

Base Information

• Chemical Name: trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide
• CAS No.: 120557-55-3
• Molecular Formula: C₂₉H₃₉FeN₃O₄P₂Si
• Molecular Weight: 639.526

Synonyms:trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide

Chemical Property of trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide

Chemical Property:

Purity/Quality:

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Technology Process of trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide

There total 3 articles about trans-(dimethylsilanediyl)(triphenylphosphine)iron⁽⁰⁾ tricarbonyl-hexamethylphosphoric triamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

(dimethylsilanediyl)iron(0) tetracarbonyl-hexamethylphosphoric triamide (120557-54-2) → trans-(dimethylsilanediyl)(triphenylphosphine)iron(0) tricarbonyl-hexamethylphosphoric triamide (120557-55-3)

Guidance literature:

With P(C₆H₅)3; In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); under Ar, standard Schlenk techniques; soln. of Fe-complex and phosphine in THF was photolyzed (-40°C, 12 h), color change to orange; evapn., orange powder, recrystn. (THF); elem. anal.;

Reference yield:

N,N,N,N,N,N-hexamethylphosphoric triamide (680-31-9) → {Fe(CO)3(P(C6H5)3)Si(OP(N(CH3)2)3)(CH3)2} (120557-55-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: tetrahydrofuran

In tetrahydrofuran;

Reference yield:

{Fe(CO)4Si(OP(N(CH3)2)3)(CH3)2} (120557-54-2) + triphenylphosphine (603-35-0) → {Fe(CO)3(P(C6H5)3)Si(OP(N(CH3)2)3)(CH3)2} (120557-55-3)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); Irradiation of a soln. of Fe(CO)4Si(CH3)2*HMPT and PPh3 at -70°C with Hg lamp. Removing of the solvent in vacuum.;

upstream raw materials:

{Fe(CO)4Si(OP(N(CH₃)2)3)(CH₃)2}

triphenylphosphine

N,N,N,N,N,N-hexamethylphosphoric triamide

(dimethylsilanediyl)iron⁽⁰⁾ tetracarbonyl-hexamethylphosphoric triamide

Downstream raw materials:

trans-Fe(CO)₃(triphenylphosphine)₂

tricarbonyl bis(triphenylphosphine) iron

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