tert-Amyl-tert-butyl nitroxide

Base Information

Chemical Name:tert-Amyl-tert-butyl nitroxide
CAS No.:28670-60-2
Molecular Formula:C₉H₂₀NO
Molecular Weight:158.264
Hs Code.:2928000090
European Community (EC) Number:631-112-3
Wikidata:Q82656965
Mol file:28670-60-2.mol

Synonyms:tert-Amyl-tert-butyl nitroxide;Nitroxide, 1,1-dimethylethyl 1,1-dimethylpropyl;SCHEMBL14142378;J-017186

Suppliers and Price of tert-Amyl-tert-butyl nitroxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TERT-AMYL-TERT-BUTYL NITROXIDE 95.00%
1G
$ 741.59

Total 2 raw suppliers

Chemical Property of tert-Amyl-tert-butyl nitroxide

Chemical Property:

Vapor Pressure:0.0931mmHg at 25°C
Refractive Index:n20/D 1.441(lit.)
Boiling Point:55-56oC5 mm Hg(lit.)
Flash Point:135 °F
PSA：3.24000
Density:0.86 g/mL at 25oC(lit.)
LogP:2.62100
Storage Temp.:2-8°C
XLogP3:2.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:159.162314293
Heavy Atom Count:11
Complexity:124

Purity/Quality:

97% ^*data from raw suppliers

TERT-AMYL-TERT-BUTYL NITROXIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22-36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC(C)(C)N(C(C)(C)C)O

Technology Process of tert-Amyl-tert-butyl nitroxide

There total 4 articles about tert-Amyl-tert-butyl nitroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 2085-66-7
3-tert-Butylamino-tert-pentylamine

: 28670-60-2
3-tert-Butyl-tert-pentylnitroxyl

Guidance literature:: With sodium tungstate; dihydrogen peroxide; In methanol; for 48h;
DOI:10.1515/znb-2000-0118

Reference yield:

: 1111-97-3
3-chloro-3-methylbut-1-yne

: 28670-60-2
3-tert-Butyl-tert-pentylnitroxyl

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / H₂O / 336000 h / 20 - 25 °C

2: 73 percent / H₂ / 5 percent Pd/C / various solvent(s) / 6 h / 17 - 25 °C / 10343 Torr

3: 87 percent / H₂O₂; Na₂WO₄*2H₂O / aq. methanol / 48 h

With sodium tungstate; water; hydrogen; dihydrogen peroxide; palladium on activated charcoal; In methanol; 1: Alkylation / 2: Catalytic hydrogenation / 3: Oxidation;
DOI:10.1515/znb-2000-0118

Reference yield:

: 1118-17-8
3-tert-Butylamino-3-methyl-1-butyne

: 28670-60-2
3-tert-Butyl-tert-pentylnitroxyl

Guidance literature:: Multi-step reaction with 2 steps

1: 73 percent / H₂ / 5 percent Pd/C / various solvent(s) / 6 h / 17 - 25 °C / 10343 Torr

2: 87 percent / H₂O₂; Na₂WO₄*2H₂O / aq. methanol / 48 h

With sodium tungstate; hydrogen; dihydrogen peroxide; palladium on activated charcoal; In methanol; 1: Catalytic hydrogenation / 2: Oxidation;
DOI:10.1515/znb-2000-0118