TROPYLIUM HEXAFLUOROPHOSPHATE

Base Information

• Chemical Name: TROPYLIUM HEXAFLUOROPHOSPHATE
• CAS No.: 29663-54-5
• Molecular Formula: C7H7F6P
• Molecular Weight: 236.097
• Mol file: 29663-54-5.mol

Synonyms:TROPYLIUM HEXAFLUOROPHOSPHATE;cycloheptatrienylium,hexafluorophosphate(1-)

Chemical Property of TROPYLIUM HEXAFLUOROPHOSPHATE

Chemical Property:

• PSA: 13.59000
• LogP: 5.25530
• Storage Temp.: 0-6°C

Purity/Quality:

98%min ^*data from raw suppliers

Tropylium Hexafluorophosphate >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 26-27-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TROPYLIUM HEXAFLUOROPHOSPHATE

There total 2 articles about TROPYLIUM HEXAFLUOROPHOSPHATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Cyclohepta-1,3,5-triene (544-25-2) → tropylium hexafluorophosphate (29663-54-5)

Guidance literature:

With nitrosyl hexafluorophosphate; In acetonitrile; for 3h; Ambient temperature;

Reference yield:

→ tropylium hexafluorophosphate (29663-54-5)

Guidance literature:

Cycloheptatrien, NH4NO3, Trifluoressigsaeureanhydrid, HF, (Oxydation); (Ausb.: 48percent);

Reference yield: 95.0%

Ru(CCPh)(1,2-bis(diphenylphosphino)ethane)Cp + tropylium hexafluorophosphate (29663-54-5) → (C5H5)Ru(CH2P(C6H5)2)2(C15H12)(1+)*PF6(1-)={(C5H5)Ru(CH2P(C6H5)2)2(C15H12)}PF6

Guidance literature:

In dichloromethane; under N2, soln. of Ru-complex (1.20 mmol) in CH2Cl2 added to suspn. of vac.-dried (C7H7)PF6 (1.48 mmol) in CH2Cl2, stirred for 20 min; evapd., extd. with CH2Cl2, filtered into excess of stirred ether, crystd. from CH2Cl2/EtOH; elem. anal.;

DOI:10.1016/0022-328X(87)80160-2

upstream raw materials:

Cyclohepta-1,3,5-triene

Downstream raw materials:

Cyclohepta-1,3,5-triene

{Re2(μ-H)4H4(triphenylphosphine)4}PF6

ReH₂(P(C₆H₅)3)3(NCCH₃)2⁽¹⁺⁾*PF₆^(1-)={ReH₂(P(C₆H₅)3)3(NCCH₃)2}PF₆

Refernces