POTASSIUM NONAFLUORO-T-BUTOXIDE

Base Information

• Chemical Name: POTASSIUM NONAFLUORO-T-BUTOXIDE
• CAS No.: 29646-16-0
• Molecular Formula: C4H F9 O . K
• Molecular Weight: 274.127
• Hs Code.: 2915900090
• Mol file: 29646-16-0.mol

Synonyms:2-Propanol,1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)-, potassium salt (8CI,9CI);Potassium perfluoro-tert-butoxide

Chemical Property of POTASSIUM NONAFLUORO-T-BUTOXIDE

Chemical Property:

• PSA: 23.06000
• LogP: 2.84260

Purity/Quality:

98% ^*data from raw suppliers

POTASSIUM NONAFLUORO-TERT-BUTOXIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of POTASSIUM NONAFLUORO-T-BUTOXIDE

There total 3 articles about POTASSIUM NONAFLUORO-T-BUTOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol (2378-02-1) → potassium perfluoro-tert-butoxide (29646-16-0)

Guidance literature:

With potassium hydride; In diethyl ether; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1039/b911758j

Reference yield: 90.8%

(trifluoromethyl)trimethylsilane (81290-20-2) + Hexafluoroacetone (684-16-2) → potassium perfluoro-tert-butoxide (29646-16-0)

Guidance literature:

With potassium fluoride; In acetonitrile; for 16h; -25 to 20 deg C;

DOI:10.1021/jo00030a018

Reference yield:

potassium hexafluorophosphate (17084-13-8) + C15H9AlF28O3Si → C12AlF28O3(1-)*K(1+) + potassium perfluoro-tert-butoxide (29646-16-0)

Guidance literature:

at 60 ℃; for 2h;

DOI:10.1039/c8sc02591f

upstream raw materials:

(trifluoromethyl)trimethylsilane

Hexafluoroacetone

1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)propan-2-ol

potassium hexafluorophosphate

Downstream raw materials:

{(2-methyl-2-phenyl-propylidene)((2,6-diisopropylphenyl)imido)molybdenum(VI)bis(perfluoro-tert-butoxide)}

C₂₀H₁₀F₁₈O₂S

Refernces

• 1、 Simonetti, Marco,Cannas, Diego M.,Panigrahi, Adyasha,Kujawa, Szymon,Kryjewski, Michal,Xie, Pan,Larrosa, Igor. "Ruthenium-Catalyzed C?H Arylation of Benzoic Acids and Indole Carboxylic Acids with Aryl Halides". . p. 549 - 553. Retrieved 2017.
• 2、 Cantalupo, Stefanie A.,Lum, June S.,Buzzeo, Marisa C.,Moore, Curtis,DiPasquale, Antonio G.,Rheingold, Arnold L.,Doerrer, Linda H.. "Three-coordinate late transition metal fluorinated alkoxide complexes". . p. 374 - 383. Retrieved 2010.
• 3、 Zhai, Feng,Bukhryakov, Konstantin V.,Schrock, Richard R.,Hoveyda, Amir H.,Tsay, Charlene,Müller, Peter. "Syntheses of Molybdenum Oxo Benzylidene Complexes". supporting information. p. 13609 - 13613. Retrieved 2018/10/20.