2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

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Chemical Name:2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose
CAS No.:1385808-54-7
Molecular Formula:C₅₆H₆₅N₅O₁₄S
Molecular Weight:1064.22
Hs Code.:

2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Synonyms:2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

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Chemical Property of 2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

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Technology Process of 2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

There total 4 articles about 2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1385808-63-8
6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

: 175728-78-6
5-(dimethylamino)-N-(prop-2-yn-1-yl)naphthalene-1-sulfonamide

: 1385808-54-7
2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Guidance literature:: With copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dichloromethane; at 20 ℃;
DOI:10.1055/s-0031-1290975

Reference yield:

: 1385808-26-3
phenyl 6-O-(2-azido)acetyl-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside

: 1385808-54-7
2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: N-iodo-succinimide / acetonitrile / 0.5 h / -40 °C / Molecular sieve

1.2: 2 h / -40 °C / Molecular sieve

2.1: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane / 20 °C

With N-iodo-succinimide; copper(ll) sulfate pentahydrate; sodium L-ascorbate; In dichloromethane; acetonitrile; 2.1: Huisgen cycloaddition;
DOI:10.1055/s-0031-1290975

Reference yield:

: 819798-14-6
phenyl 2,3,4-tri-O-benzyl-6-O-chloroacetyl-1-thio-β-D-galactopyranoside

: 1385808-54-7
2,3,4-tri-O-benzyl-6-O-{4-[(5-dimethylaminonaphthalene-1-sulfonylamino)methyl]-1H-1,2,3-triazol-1-yl}acetyl-β-D-galactopyranosyl-(1->6)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium azide; potassium iodide / acetone / 24 h / 20 °C

2.1: N-iodo-succinimide / acetonitrile / 0.5 h / -40 °C / Molecular sieve

2.2: 2 h / -40 °C / Molecular sieve

3.1: copper(ll) sulfate pentahydrate; sodium L-ascorbate / dichloromethane / 20 °C

With N-iodo-succinimide; sodium azide; copper(ll) sulfate pentahydrate; sodium L-ascorbate; potassium iodide; In dichloromethane; acetone; acetonitrile; 3.1: Huisgen cycloaddition;
DOI:10.1055/s-0031-1290975