2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Base Information

Chemical Name:2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione
CAS No.:1287221-38-8
Molecular Formula:C₁₂H₁₃BBrNO₅
Molecular Weight:341.954
Hs Code.:

Synonyms:2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Suppliers and Price of 2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 5 raw suppliers

Chemical Property of 2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Chemical Property:

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

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Technology Process of 2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

There total 1 articles about 2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 4408-64-4
N-methyliminodiacetic acid

: 89694-45-1
5-bromo-2-methoxyphenylboronic acid

: 1287221-38-8
2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

Guidance literature:: In dimethyl sulfoxide; toluene; for 6h; Reflux;
DOI:10.1039/c0ob00847h

Reference yield: 61.0%

: 1287221-38-8
2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

: 108957-20-6
(R)-N-(tert-butoxycarbonyl)-3-iodoalanine benzyl ester

: (S)-benzyl 2-(tert-butoxycarbonylamino)-3-(4-methoxy-3-(6-methyl-4,8-dioxo-1,3,6,2-dioxazaborocan-2-yl)phenyl)propanoate

Guidance literature:: (R)-N-(tert-butoxycarbonyl)-3-iodoalanine benzyl ester; With iodine; zinc; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere; Exothermic reaction;

2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione; With tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 50 ℃; for 6h; Inert atmosphere;
DOI:10.1039/c0ob00847h

Reference yield: 59.0%

: 1287221-38-8
2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

: 108957-20-6,125942-79-2
benzyl 2(S)-<(tert-butoxycarbonyl)amino>-3-iodopropionate

: (R)-benzyl 2-(tert-butoxycarbonylamino)-3-(4-methoxy-3-(6-methyl-4,8-dioxo-1,3,6,2-dioxazaborocan-2-yl)phenyl)propanoate

Guidance literature:: benzyl 2(S)-<(tert-butoxycarbonyl)amino>-3-iodopropionate; With iodine; zinc; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere; Exothermic reaction;

2-(5-bromo-2-methoxyphenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione; With tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 50 ℃; for 6h; Inert atmosphere;
DOI:10.1039/c0ob00847h