Me₃SiAs=C(NMe₂)2

Base Information

Chemical Name:Me₃SiAs=C(NMe₂)2
CAS No.:175650-29-0
Molecular Formula:C₈H₂₁AsN₂Si
Molecular Weight:248.275
Hs Code.:

Synonyms:Me₃SiAs=C(NMe₂)2

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Chemical Property of Me₃SiAs=C(NMe₂)2

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Technology Process of Me₃SiAs=C(NMe₂)2

There total 1 articles about Me₃SiAs=C(NMe₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 19348-30-2
N,N,N',N',S-pentamethylthiuronium iodide

: lithium bis(trimethylsilyl)arsanide-tetrahydrofuran (1/2)

: 17729-30-5
tris(trimethylsilyl)arsane

: 175650-29-0
Me₃SiAs=C(NMe₂)2

Guidance literature:: In pentane; Yield given. Title compound not separated from byproducts; 1) -35 deg C, 2 h, 2) r.t., 1 h;

Reference yield: 75.0%

: 103310-49-2
(η5-C5H5)(CO)2WPC(SiMe3)2

: 98-88-4
benzoyl chloride

: 175650-29-0
Me₃SiAs=C(NMe₂)2

: 882978-84-9
[Cp(CO)2W-As=C(Ph)-O-P-O-C(Ph)=As-C(SiMe₃)2]

Guidance literature:: In diethyl ether; pentane; byproducts: (Me2N)2C=C(NMe2)2; under N2; benzoyl chloride in Et2O was combined with Me3SiAsC(NMe2)2 in n-pentane; stirring at -30°C (30 min) to give PhC(O)AsC(NMe2)2 which was added dropwise to soln. of W-contg. compd. in Et2O at -30°C; stirring at -20°C (4 h); after stirring at 20°C (12 h) volatiles were removed in vac.; residue was dissolved with Et2O; Florisil was added; slurry was concd. to dryness; column chromy. (Florisil, Et2O/n-pentane (1:1)); concn., storingat -30°C; elem. anal.;
DOI:10.1021/om051084t

Reference yield: 54.0%

: 103310-49-2
(η5-C5H5)(CO)2WPC(SiMe3)2

: 175650-29-0
Me₃SiAs=C(NMe₂)2

: 938-18-1
mesitylene-2-carboxylic acid chloride

: [Cp(CO)2W-P-O-C(Mes)=As-C(SiMe₃)2]

: [Cp(CO)2W(η3-MesC(O)AsPC(SiMe3)2)]

Guidance literature:: In diethyl ether; pentane; under N2; MesC(O)AsC(NMe2)2 was formed as a slurry at -30°C by slow react. of MesC(O)Cl in Et2O and Me3SiAsC(NMe2)2 in n-pentane; stirring at -30°C; slurry was added dropwise to a soln. of W-contg. compd. in Et2O (1:1), (-30°C); detd. by (31)P NMR spectra studies after stirring for 4 h at -30°C and 12 h at ambient temp.; the solvent and volatiles were removed; column chromy. (Florisil, Et2O/pentane); concn. and storage at -30°C; elem. anal.;
DOI:10.1021/om051084t