p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide

Base Information

• Chemical Name: p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide
• CAS No.: 905454-03-7
• Molecular Formula: C₁₀H₄F₉IO₄S₂
• Molecular Weight: 550.161
• Mol file: 905454-03-7.mol

Synonyms:p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide

Chemical Property of p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide

There total 2 articles about p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide (905453-88-5) + 4-Iodobenzotrifluoride (455-13-0) → p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide (905454-03-7)

Guidance literature:

dirhodium tetraacetate; at 40 ℃; for 0.0833333h;

DOI:10.1021/ja074624h

Reference yield: 77.0%

4-Iodobenzotrifluoride (455-13-0) + phenyliodonium bis(trifluoromethylsulfonyl)methylide (132273-36-0) → p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide (905454-03-7)

Guidance literature:

With dirhodium tetraacetate; at 90 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ol800211x

Reference yield: 86.0%

iodobenzene (591-50-4) + p-(trifluoromethyl)phenyliodonium bis(trifluoromethylsulfonyl)methylide (905454-03-7) → phenyliodonium bis(trifluoromethylsulfonyl)methylide (132273-36-0)

Guidance literature:

With dirhodium tetraacetate; 4-Iodobenzotrifluoride; In α,α,α-trifluorotoluene; at 125 ℃; for 10h; Inert atmosphere;

DOI:10.1021/ol800211x

upstream raw materials:

4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide

4-Iodobenzotrifluoride

phenyliodonium bis(trifluoromethylsulfonyl)methylide

Downstream raw materials:

phenyliodonium bis(trifluoromethylsulfonyl)methylide