(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Base Information

Chemical Name:(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine
CAS No.:864443-52-7
Molecular Formula:C₁₄H₁₂F₃NO₄S₂
Molecular Weight:379.381
Hs Code.:

Synonyms:(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Suppliers and Price of (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Chemical Property:

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Technology Process of (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

There total 1 articles about (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 4381-25-3
S-methyl-S-phenylsulfoximine

: 103008-51-1
2-(trifluoromethoxy)benzenesulfonyl chloride

: 864443-52-7
(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Guidance literature:: With pyridine; at 70 ℃; for 2h;
DOI:10.1021/jo050747d

Reference yield: 42.0%

: 864443-52-7
(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

: 124-38-9,18923-20-1
carbon dioxide

: 864443-60-7
(+/-)-S-carboxymethyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Guidance literature:: (+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

carbon dioxide; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;
DOI:10.1021/jo050747d

Reference yield:

: 864443-52-7
(+/-)-S-methyl-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

: (+/-)-(S_RS,RS)-S-(2-phenylbut-3-enyl)-S-phenyl-N-[2-(trifluoromethoxy)benzenesulfonyl]sulfoximine

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 42 percent / tetrahydrofuran; hexane / 0.5 h / -78 °C

2.1: 57 percent / 1-(dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride / CH₂Cl₂ / 16 h / 0 - 20 °C

3.1: N,O-bis(trimethylsilyl)acetamide; KOAc / toluene / 8 h / Heating

With n-butyllithium; N,O-bis-(trimethylsilyl)-acetamide; potassium acetate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In tetrahydrofuran; hexane; dichloromethane; toluene; 3.1: decarboxylative Claisen rearrangement;
DOI:10.1021/jo050747d