IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)

Base Information

• Chemical Name: IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)
• CAS No.: 150266-23-2
• Molecular Formula: C₄₉H₅₀IrP₃S
• Molecular Weight: 956.143
• Mol file: 150266-23-2.mol

Synonyms:IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)

Chemical Property of IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅)

There total 6 articles about IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)(1+)*B(C6H5)4(1-)={Ir(CH3C(CH2P(C6H5)2)3)(C8H6S)}{B(C6H5)4} → IrH2(CH3C(CH2P(C6H5)2)3)(SC6H4C2H5) (150266-23-2)

Guidance literature:

With H₂; In tetrahydrofuran; byproducts: triphenylboron, benzene; under N2; a soln. of the Ir complex in THF was pressurized with H2 to 5 atm at room temp. for 3 h; volatiles were removed in vac., crystd. from THF and ethanol, filtered , washed with ethanol and pentane; elem. anal.;

DOI:10.1021/ja00089a027

Reference yield:

{(triphos)Ir(η2-C,S-C8H6S)}BPh4*1.5THF*0.5EtOH → IrH2(CH3C(CH2P(C6H5)2)3)(SC6H4C2H5) (150266-23-2)

Guidance literature:

With H₂; In tetrahydrofuran; byproducts: BPh3, benzene; High Pressure; 5 atm of H2, 20°C, 3 h; BPh3 extd. either by sublimation or with n-pentane, NMR;

DOI:10.1021/ja00069a061

Reference yield:

Ir(CH3C(CH2P(C6H5)2)3)(SC6H4CHCH3)(1+)*B(C6H5)4(1-)={Ir(CH3C(CH2P(C6H5)2)3)(SC6H4CHCH3)}{B(C6H5)4} (155806-23-8) → IrH2(CH3C(CH2P(C6H5)2)3)(SC6H4C2H5) (150266-23-2)

Guidance literature:

With H₂; In tetrahydrofuran; byproducts: triphenylboron, benzene; a soln. of the Ir complex in THF was stirred under H2 (1-5 atm) at room temp. for 3 h; concd. to dryness under vac.;

DOI:10.1021/ja00089a027

upstream raw materials:

Ir(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄CHCH₃)⁽¹⁺⁾*B(C₆H₅)4^(1-)={Ir(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄CHCH₃)}{B(C₆H₅)4}

CH₃C[CH₂P(C₆H₅)2]3IrH₂(SC₆H₄CHCH₂)

hydrogen

Benzo[b]thiophene

Downstream raw materials:

Ir(1,1,1-tris(diphenylphosphinomethyl)ethane)Cl₂H