[2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel

Base Information

• Chemical Name: [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel
• CAS No.: 131214-90-9
• Molecular Formula: C₄₄H₂₀Br₈N₄Ni
• Molecular Weight: 1302.59
• Mol file: 131214-90-9.mol

Synonyms:[2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel

Chemical Property of [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel

There total 7 articles about [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

N-Bromosuccinimide (128-08-5) + 5,10,15,20-tetraphenylporphinatonickel(II) (14172-92-0) → (2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato)nickel(II) (131214-90-9)

Guidance literature:

In further solvent(s); under Ar atm. to soln. Ni(TPP) in o-dichlorobenzene was added N-bromosuccinimide (1:12) and refluxed for 2-3 h; solvent was distilled off, residue was dissolved in CH2Cl2/MeOH (1:1) and chromed. on alumina, product was recrystd. from CH2Cl2/MeOH; elem. anal.;

DOI:10.1021/ic000738h

Reference yield: 70.0%

5,10,15,20-tetraphenylporphinatonickel(II) (14172-92-0) → (2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato)nickel(II) (131214-90-9)

Guidance literature:

With N-Bromosuccinimide; In chloroform; N,N-dimethyl-formamide; for 0.0666667h; Reflux;

DOI:10.1134/S1070428017070235

Reference yield: 25.0%

(tetraphenylporphyrinato)nickel(II) (14172-92-0) + potassium bromide (7558-02-3,7758-02-3) → [2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrinato]nickel (131214-90-9)

Guidance literature:

With ammonium molibdate; perchloric acid; dihydrogen peroxide; In dichloromethane; water; at 25 ℃; for 18h; pH=1;

DOI:10.1039/c9nj02503k

upstream raw materials:

N-Bromosuccinimide

5,10,15,20-tetraphenylporphinatonickel(II)

nickel(II) acetate tetrahydrate

5,15,10,20-tetraphenylporphyrin