1-Oxo-2,2-dimethyl-1,2-dihydronaphthalene

Base Information

Chemical Name:1-Oxo-2,2-dimethyl-1,2-dihydronaphthalene
CAS No.:16020-15-8
Molecular Formula:C₁₂H₁₂O
Molecular Weight:172.227
Hs Code.:
European Community (EC) Number:874-964-3
Nikkaji Number:J2.481.041K

Synonyms:1-oxo-2,2-dimethyl-1,2-dihydronaphthalene;16020-15-8;2,2-dimethylnaphthalen-1-one;2,2-dimethyl-2h-naphthalen-1-one;SCHEMBL4228062;MVWSDWVTRYPWLS-UHFFFAOYSA-N;2,2-Dimethylnaphthalen-1(2H)-one;2,2-dimethyl-1,2-dihydronaphthalen-1-one;2,2-dimethyl-1-oxo-1,2-dihydronaphthalene;EN300-8239386

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Oxo-2,2-dimethyl-1,2-dihydronaphthalene

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:172.088815002
Heavy Atom Count:13
Complexity:250

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C=CC2=CC=CC=C2C1=O)C

Technology Process of 1-Oxo-2,2-dimethyl-1,2-dihydronaphthalene

There total 1 articles about 1-Oxo-2,2-dimethyl-1,2-dihydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 1-isopropyl-2-methylisoquinolinium iodide

: 2,2-dimethyl-3-methylamino-3,4-dihydronaphthalen-1(2H)-one

: 4594-71-2
N-methylisocarbostyril

: 1314734-79-6
2,2-dimethyl-3,4-dihydronaphthalen-1(2H)-on-3-ol

: 16020-15-8
1-oxo-2,2-dimethyl-1,2-dihydronaphthalene

Guidance literature:: 1-isopropyl-2-methylisoquinolinium iodide; With water; sodium hydroxide; at 150 ℃; for 9h; Sealed ampoule;

With hydrogenchloride; water; at 20 ℃; for 0.5h;
DOI:10.1007/s10593-011-0722-3

Reference yield:

: 16020-15-8
1-oxo-2,2-dimethyl-1,2-dihydronaphthalene

: 573-98-8
dimethyl-1,2 naphtalene

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / phosphorous pentasulfide / pyridine / 90 °C

2: 45 percent / W(CO)6 / chlorobenzene / 24 h / Heating

With tungsten hexacarbonyl; phosphorous (V) sulfide; In pyridine; chlorobenzene;
DOI:10.1021/jo00293a037

Reference yield:

: 16020-15-8
1-oxo-2,2-dimethyl-1,2-dihydronaphthalene

: (1S,9R)-13,13-Dimethyl-11-phenyl-10,12-dioxa-11-bora-tricyclo[7.3.1.0^2,7]trideca-2⁽⁷⁾,3,5-triene

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / NaHPO₄; NaOCl / (R,R)-{1,2-bis[3,5-(tBu)2-salicylideneamino]cyclohexane}MnCl / CH₂Cl₂; H₂O / 72 h / 0 °C / pH 11

2: 98 percent / hydrogen; methanol / Pd/C / ethyl acetate / 0.17 h

3: 267 mg / diisobutylaluminum hydride / tetrahydrofuran; hexane / 0.5 h / -78 °C

With methanol; sodium hypochlorite; camphor-10-sulfonic acid; hydrogen; diisobutylaluminium hydride; palladium on activated charcoal; (R,R)-(-)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexandiamino-manganese(III) chloride; In tetrahydrofuran; hexane; dichloromethane; water; ethyl acetate; 1: Jacobsen epoxidation;
DOI:10.1016/S0040-4020(03)01127-X