(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf)

Base Information

• Chemical Name: (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf)
• CAS No.: 1036029-60-3
• Molecular Formula: CF₃O₃S*C₄₈H₃₈NO₃PRh
• Molecular Weight: 959.784
• Mol file: 1036029-60-3.mol

Synonyms:(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf)

Chemical Property of (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf)

There total 1 articles about (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)(OTf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh3)Cl (1036029-64-7) + silver trifluoromethanesulfonate (2923-28-6) → (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh3)(OTf) (1036029-60-3)

Guidance literature:

In dichloromethane; under Ar; Rh complex and Ag compd. dissolved in CH2Cl2; suspn. stirred for 12 h; filtered over plug of celite; CH2Cl2 removed under reduced pressure; recrystd. from acetone/n-hexane; dried in vac.;

DOI:10.1002/anie.200704685

Reference yield:

(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh3)(OTf) (1036029-60-3) → (rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amide)(OPPh3) (1036029-61-4)

Guidance literature:

With KOtBu or Li[N(SiMe₃)2]; byproducts: tBuOH, KOTf; deprotonation;

DOI:10.1002/anie.200704685

upstream raw materials:

(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amine)(OPPh₃)Cl

silver trifluoromethanesulfonate

Downstream raw materials:

(rhodium(I))(bis(5-H-dibenzo[a,d]cyclopenten-5-yl)amide)(OPPh₃)