(CO)5CrC(Ph)NEt₂

Base Information

Chemical Name:(CO)5CrC(Ph)NEt₂
CAS No.:117041-17-5
Molecular Formula:C₁₆H₁₅CrNO₅
Molecular Weight:353.295
Hs Code.:

Synonyms:(CO)5CrC(Ph)NEt₂

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Chemical Property of (CO)5CrC(Ph)NEt₂

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Technology Process of (CO)5CrC(Ph)NEt₂

There total 2 articles about (CO)5CrC(Ph)NEt₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: disodium pentacarbonylchromium

: 1696-17-9
N,N-diethylbenzamide

: 117041-17-5
(CO)5CrC(Ph)NEt₂

Guidance literature:: With chloro-trimethyl-silane; In not given; react. of 1.2-2 equiv. Na2Cr(CO)5 / equiv. of amide from -78°C to 0°C, then addn. of TMSCl, -78°C;

Reference yield:

: 27436-93-7
pentacarbonyl(1-methoxybenzylidene)chromium⁽⁰⁾

: 109-89-7
diethylamine

: 117041-17-5
(CO)5CrC(Ph)NEt₂

Guidance literature:: In tetrahydrofuran; Amine was added to a THF soln. of (CO)5CrC(OCH3)C6H5 complex. After stirring at -78 to 25°C the solvent was removed under vac..; elem.anal.;
DOI:10.1021/ja00233a018

Reference yield: 100.0%

: 117041-17-5
(CO)5CrC(Ph)NEt₂

: 105394-78-3
2-(N,N-diethylamino)-2-phenylacetic acid methyl ester

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

Guidance literature:: With methanol; In methanol; Irradiation (UV/VIS); solid carbene complex in dry methanol is added to an oven-dried Pyrex pressure tube, contents are degassed, purged with Ar, warmed to room temp., purged with CO, pressurized with 50-90 psi CO, irradiated (450 W) for 5 d; monitored by TLC, mixt. is filtered (Celite) to remove solid Cr(CO)6, evapn. in vacuo, air oxidn. overnight, filtn.; NMR, IR, elem. anal.;