2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose

Base Information

• Chemical Name: 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose
• CAS No.: 530114-05-7
• Molecular Formula: C₃₈H₄₁NO₆S
• Molecular Weight: 639.813
• Mol file: 530114-05-7.mol

Synonyms:2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose

Chemical Property of 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose

There total 1 articles about 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + N-allyl isothiocyanate (57-06-7,58391-87-0) → 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose (530114-05-7) + 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-α-D-glucopyranose

Guidance literature:

With 4 A molecular sieve; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In N,N,N,N,N,N-hexamethylphosphoric triamide; toluene; at 20 ℃; for 4h; Title compound not separated from byproducts;

Reference yield: 89.0%

(+/-)-2-pentanol (6032-29-7,13403-73-1) + 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose (530114-05-7) → 2-pentyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside

Guidance literature:

With bromine; lithium perchlorate; sodium hydrogencarbonate; 4 A molecular sieve; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at -25 ℃; for 0.166667h;

Reference yield: 89.0%

cyclohexanol (108-93-0) + 2,3,4,6-tetra-O-benzyl-1-O-(N-allylthiocarbamoyl)-β-D-glucopyranose (530114-05-7) → cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside (56632-55-4)

Guidance literature:

With bromine; sodium hydrogencarbonate; lithium trifluoromethanesulfonate; 4 A molecular sieve; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; at -25 ℃; for 0.166667h;

upstream raw materials:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

N-allyl isothiocyanate

Downstream raw materials:

methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside

tert-butyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside

cyclohexyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside