2-azido-5-chlorobenzaldehyde ethylene dithioacetal

Base Information

• Chemical Name: 2-azido-5-chlorobenzaldehyde ethylene dithioacetal
• CAS No.: 916664-22-7
• Molecular Formula: C₉H₈ClN₃S₂
• Molecular Weight: 257.768
• Mol file: 916664-22-7.mol

Synonyms:2-azido-5-chlorobenzaldehyde ethylene dithioacetal

Chemical Property of 2-azido-5-chlorobenzaldehyde ethylene dithioacetal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-azido-5-chlorobenzaldehyde ethylene dithioacetal

There total 1 articles about 2-azido-5-chlorobenzaldehyde ethylene dithioacetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

2-azido 5-chlorobenzaldehyde (916664-23-8) + ethane-1,2-dithiol (540-63-6) → 2-azido-5-chlorobenzaldehyde ethylene dithioacetal (916664-22-7)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 4h;

DOI:10.1021/ol062373w

Reference yield: 90.0%

2-azido-5-chlorobenzaldehyde ethylene dithioacetal (916664-22-7) + triphenylphosphine (603-35-0) → 5-chloro-2-(triphenylphosphoranylideneamino)benzaldehyde ethylene dithioacetal (916664-17-0)

Guidance literature:

In diethyl ether; at 20 ℃; for 16h;

DOI:10.1021/ol062373w

Reference yield:

2-azido-5-chlorobenzaldehyde ethylene dithioacetal (916664-22-7) → (4-chloro-2-[1,3]dithiolan-2-yl-phenyl)-diphenylvinylidene-amine

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / diethyl ether / 16 h / 20 °C

2: CH₂Cl₂ / 0.5 h / 20 °C

In diethyl ether; dichloromethane;

DOI:10.1021/ol062373w

upstream raw materials:

2-azido 5-chlorobenzaldehyde

ethane-1,2-dithiol

Downstream raw materials:

5-chloro-2-(triphenylphosphoranylideneamino)benzaldehyde ethylene dithioacetal