(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Base Information

Chemical Name:(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione
CAS No.:1349697-68-2
Molecular Formula:C₃₂H₂₆O₅
Molecular Weight:490.555
Hs Code.:

Synonyms:(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Suppliers and Price of (R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

There total 7 articles about (R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1349697-70-6
(R)-3-(1,5-bis(benzyloxy)-9,10-dioxo-9,10-dihydroanthracen-2-yl)-2-hydroxy-2-methylpropyl 4-methylbenzenesulfonate

: 1349697-68-2
(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; at 0 - 20 ℃;
DOI:10.1021/ol203041b

Reference yield:

: 1349697-67-1
1,5-bis(benzyloxy)-2-(2-methylallyl)anthracene-9,10-dione

: 1349697-68-2
(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: Multi-step reaction with 3 steps

1: osmium(VIII) oxide; hydroquinidine 1 4-phthalazinediyl diether; potassium carbonate; potassium hexacyanoferrate(III) / water; tert-butyl alcohol / 0 - 20 °C

2: di(n-butyl)tin oxide; triethylamine / dichloromethane / 0 - 20 °C

3: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C

With osmium(VIII) oxide; hydroquinidine 1 4-phthalazinediyl diether; sodium hydride; di(n-butyl)tin oxide; potassium carbonate; triethylamine; potassium hexacyanoferrate(III); In tetrahydrofuran; dichloromethane; water; mineral oil; tert-butyl alcohol; 1: Sharpless dihydroxylation;
DOI:10.1021/ol203041b

Reference yield:

: 1349697-69-3
(R)-1,5-bis(benzyloxy)-2-(2,3-dihydroxy-2-methylpropyl)anthracene-9,10-dione

: 1349697-68-2
(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: Multi-step reaction with 2 steps

1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 0 - 20 °C

2: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C

With sodium hydride; di(n-butyl)tin oxide; triethylamine; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1021/ol203041b