(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

Base Information

Chemical Name:(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione
CAS No.:1349697-71-7
Molecular Formula:C₃₃H₂₆O₆
Molecular Weight:518.566
Hs Code.:

Synonyms:(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

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Chemical Property of (R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

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Technology Process of (R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

There total 9 articles about (R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 201230-82-2
carbon monoxide

: 1349697-68-2
(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

: 1349697-71-7
(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: With bis(tetrahydrofuran)-meso-tetra(4-chlorophenyl)porphyrinato aluminum tetracarbonyl cobaltate; In tetrahydrofuran; at 40 ℃; for 20h; under 46544.6 Torr;
DOI:10.1021/ol203041b

Reference yield: 70.0%

: 1349697-68-2
(R)-1,5-bis(benzyloxy)-2-((2-methyloxiran-2-yl)methyl)anthracene-9,10-dione

: 1349697-71-7
(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: With carbon monoxide; C₁₈H₁₅P*AlH⁽²⁺⁾*2C₄H₈O*Cl^(1-)*Co⁽³⁺⁾*4CO^(1-); In tetrahydrofuran; at 40 ℃; for 20h; under 46544.6 Torr; stereospecific reaction; Glovebox;
DOI:10.1039/c3cc44050h

Reference yield:

: 1349697-67-1
1,5-bis(benzyloxy)-2-(2-methylallyl)anthracene-9,10-dione

: 1349697-71-7
(R)-1,5-bis(benzyloxy)-2-((2-methyl-4-oxooxetan-2-yl)methyl)anthracene-9,10-dione

Guidance literature:: Multi-step reaction with 4 steps

1: osmium(VIII) oxide; hydroquinidine 1 4-phthalazinediyl diether; potassium carbonate; potassium hexacyanoferrate(III) / water; tert-butyl alcohol / 0 - 20 °C

2: di(n-butyl)tin oxide; triethylamine / dichloromethane / 0 - 20 °C

3: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C

4: bis(tetrahydrofuran)-meso-tetra(4-chlorophenyl)porphyrinato aluminum tetracarbonyl cobaltate / tetrahydrofuran / 20 h / 40 °C / 46544.6 Torr

With osmium(VIII) oxide; hydroquinidine 1 4-phthalazinediyl diether; bis(tetrahydrofuran)-meso-tetra(4-chlorophenyl)porphyrinato aluminum tetracarbonyl cobaltate; sodium hydride; di(n-butyl)tin oxide; potassium carbonate; triethylamine; potassium hexacyanoferrate(III); In tetrahydrofuran; dichloromethane; water; mineral oil; tert-butyl alcohol; 1: Sharpless dihydroxylation;
DOI:10.1021/ol203041b