[Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

Base Information

Chemical Name:[Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]
CAS No.:390802-17-2
Molecular Formula:C₄₈H₃₈Cl₂N₄O₂Ru
Molecular Weight:874.831
Hs Code.:

[Ru((C<sub>12</sub>H<sub>6</sub>N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OCH<sub>3</sub>)CH<sub>2</sub>CH<sub>2</sub>)2C<sub>6</sub>H<sub>4</sub>Cl<sub>2</sub>]

Synonyms:[Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

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Chemical Property of [Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

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Technology Process of [Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

There total 1 articles about [Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 30066-40-1,939024-67-6,134001-83-5
{RuCl₂(NCMe)4}

: 390802-35-4
((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄

: 390802-17-2
[Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

Guidance literature:: In 1,2-dichloro-ethane; under Ar; soln. of ligand in ClCH2CH2Cl and soln. of Ru(CH3CN)4Cl2 in ClCH2CH2Cl added dropwise to ClCH2CH2Cl under reflux with vigorous stirring (special high diln. glassware), mixt. heated at 83°C under reflux for 2 h; evapn., flash chromy. (silica, CH2Cl2/CH3OH);
DOI:10.1021/ja011250y

Reference yield: 80.0%

: 17084-13-8
potassium hexafluorophosphate

: 1134-35-6
4,4'-dimethyl-2,2'-bipyridines

: 390802-17-2
[Ru((C₁₂H₆N₂C₆H₄OCH₃)CH₂CH₂)2C₆H₄Cl₂]

: [Ru((C₁₂H₆N₂(4-CH₃OC₆H₄)CH₂CH₂)2C₆H₄)(4,4'-dimethyl-2,2'-bipyridine)](hexafluorophosphate)2

Guidance literature:: In ethanol; water; under Ar; the bipyridine was added to a suspn. of the Ru complex in CH3CH2OH/H2O, mixt. was heated under reflux for 2 h, soln. was cooled, a saturated aq. soln. of KPF6 was added; ethanol was evapd., ppt. was filtered off under vac., chromy. (SiO2, gradient of CH3CN/H2O/saturated KNO3), orange fractions combined, dissolvedin acetone, aq. soln. of KPF6 was added, acetone was evapd., ppt. was f iltered off under vac.;
DOI:10.1021/ja011250y