[Mo(CO)4(Ph₂PCMe₂PPh₂)]

Base Information

Chemical Name:[Mo(CO)4(Ph₂PCMe₂PPh₂)]
CAS No.:89198-83-4
Molecular Formula:C₃₁H₂₆MoO₄P₂
Molecular Weight:620.433
Hs Code.:

[Mo(CO)4(Ph<sub>2</sub>PCMe<sub>2</sub>PPh<sub>2</sub>)]

Synonyms:[Mo(CO)4(Ph₂PCMe₂PPh₂)]

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Chemical Property of [Mo(CO)4(Ph₂PCMe₂PPh₂)]

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Technology Process of [Mo(CO)4(Ph₂PCMe₂PPh₂)]

There total 4 articles about [Mo(CO)4(Ph₂PCMe₂PPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 82328-55-0
[Mo(CO)4(Ph₂PCHMePPh₂)]

: 917-54-4
methyllithium

: 74-88-4
methyl iodide

: 89198-83-4
[Mo(CO)4(Ph₂PCMe₂PPh₂)]

Guidance literature:: In tetrahydrofuran; (N2); addn. of MeLi to soln. of Mo(CO)4(Ph2PCH(Me)PPh2) in THF; stirringfor 1 h; addn. of MeI; stirring overnight; removal of volatiles under vac., dissolving in CH2Cl2; washing with H2O;drying of CH2Cl2 soln. over MgSO4; filtration, concn. on a rotary evapo rator; addn. of MeOH; placing in the freezer; crystn.;
DOI:10.1016/j.jorganchem.2007.09.024

Reference yield: 81.0%

: 26743-81-7
tetracarbonyl-bis(diphenylphosphino)methane-molybdenum⁽⁰⁾

: 89198-83-4
[Mo(CO)4(Ph₂PCMe₂PPh₂)]

Guidance literature:: With N,N,N,N,-tetramethylethylenediamine; methyllithium; methyl iodide; In diethyl ether; benzene; a soln. of methyl-lithium in Et2O was added to a stirred soln. of Mo-compd. and N,N,N',N'-tetramethylethylenediamine in benzene; the mixt. was stirred for 1 h at 20°C, then CH3I was added; stirring at 70-75°C for 5 h;; the resultant mixt. was then cooled to 0°C, H2O was added and the product isolated; recrystn. from CH2Cl2/MeOH; elem.anal.;;
DOI:10.1016/S0020-1693(00)81432-2

Reference yield: 16.0%

: 59967-36-1,65337-26-0
cis-tetracarbonylbis(piperidine)molybdenum

: 57585-26-9
2,2’-bis(diphenylphosphino)propane

: 89198-83-4
[Mo(CO)4(Ph₂PCMe₂PPh₂)]

Guidance literature:: In dichloromethane; (N2); reflux of Mo(CO)4(NHC5H10)2 and Ph2PCMe2PPh2 in CH2Cl2 for 1 h; according to: "S. Al-Jibori, B. L. Shaw, Inorg. Chim. Acta 74 (1983) 235"; cooling, filtration, concn. on rotary evaporator; addn. of MeOH; placingin freezer overnight; crystn.;
DOI:10.1016/j.jorganchem.2007.09.024