C₂₃H₃₈O₂SSi

Base Information

• Chemical Name: C₂₃H₃₈O₂SSi
• CAS No.: 1542794-53-5
• Molecular Formula: C₂₃H₃₈O₂SSi
• Molecular Weight: 406.705
• Mol file: 1542794-53-5.mol

Synonyms:C₂₃H₃₈O₂SSi

Chemical Property of C₂₃H₃₈O₂SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₃₈O₂SSi

There total 5 articles about C₂₃H₃₈O₂SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C17H24O2S (1542794-50-2) + tert-butyldimethylsilyl chloride (18162-48-6) → C23H38O2SSi (1542794-53-5)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.tetlet.2013.12.040 DOI:10.1016/j.tetlet.2013.12.040

Reference yield:

C15H20O2S (1373398-07-2) → C23H38O2SSi (1542794-53-5)

Guidance literature:

Multi-step reaction with 4 steps

1: triethylamine; dmap / dichloromethane / 0.08 h / 0 °C

2: titanium(IV) dichlorodiisopropylate / toluene / 2.5 h / -45 °C

3: sodium tetrahydroborate / methanol / 0.08 h / -10 °C

4: 1H-imidazole / dichloromethane / 1 h / 20 °C

With 1H-imidazole; dmap; sodium tetrahydroborate; titanium(IV) dichlorodiisopropylate; triethylamine; In methanol; dichloromethane; toluene; 2: |Ferrier Carbohydrate Rearrangement;

DOI:10.1016/j.tetlet.2013.12.040

Reference yield:

C15H18O2S (1373398-06-1) → C23H38O2SSi (1542794-53-5)

Guidance literature:

Multi-step reaction with 5 steps

1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.08 h / -10 °C

2: triethylamine; dmap / dichloromethane / 0.08 h / 0 °C

3: titanium(IV) dichlorodiisopropylate / toluene / 2.5 h / -45 °C

4: sodium tetrahydroborate / methanol / 0.08 h / -10 °C

5: 1H-imidazole / dichloromethane / 1 h / 20 °C

With 1H-imidazole; dmap; sodium tetrahydroborate; titanium(IV) dichlorodiisopropylate; cerium(III) chloride heptahydrate; triethylamine; In methanol; dichloromethane; toluene; 1: |Luche Cerium Reduction / 3: |Ferrier Carbohydrate Rearrangement;

DOI:10.1016/j.tetlet.2013.12.040

upstream raw materials:

C₁₅H₁₈O₂S

C₁₅H₂₀O₂S

C₁₇H₂₂O₃S

C₁₇H₂₂O₂S

Downstream raw materials:

C₂₃H₃₈O₄SSi