(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

Base Information

Chemical Name:(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene
CAS No.:139640-17-8
Molecular Formula:C₂₂H₃₀O
Molecular Weight:310.48
Hs Code.:

(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0<sup>1,5</sup>>undec-2-ene

Synonyms:(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

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Chemical Property of (1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

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Technology Process of (1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

There total 1 articles about (1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 100-39-0
benzyl bromide

: 139640-15-6,139686-89-8
(1S,5R,7R,8S)-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-en-8-ol

: 139640-17-8
(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

Guidance literature:: With sodium hydride; 1.) THF, 2 h, reflux, 2.) THF, 15 h, reflux;
DOI:10.1246/bcsj.65.203

Reference yield: 61.0%

: 139640-17-8
(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

: 139640-18-9
(1S,2R,3R,5R,7R, 8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undecan-3-ol

Guidance literature:: With diborane; In tetrahydrofuran; for 4h; Ambient temperature;
DOI:10.1246/bcsj.65.203

Reference yield:

: 139640-17-8
(1S,5R,5R,8S)-8-benzyloxy-2,6,6,7-tetramethyltricyclo<5.2.2.0^1,5>undec-2-ene

: 139640-16-7
(3S,3aR,6R,7aR,9S)-9-Benzyloxy-3,6,7,7-tetramethyl-octahydro-3a,6-ethano-indene

Guidance literature:: Multi-step reaction with 3 steps

1: 61 percent / 1.) diborane / tetrahydrofuran / 4 h / Ambient temperature

2: 95 percent / Et₃N / CH₂Cl₂ / Ambient temperature

3: 75 percent / LiAlH₄ / diethyl ether / 24 h / Heating

With lithium aluminium tetrahydride; triethylamine; diborane; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1246/bcsj.65.203