5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Base Information

Chemical Name:5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate
CAS No.:428861-10-3
Molecular Formula:C₁₉H₁₂F₆O₇S₂
Molecular Weight:530.422
Hs Code.:

Synonyms:5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Suppliers and Price of 5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

There total 6 articles about 5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: (R)-5',6'-benzo-6-methoxy-2,2'-biphenol

: 428861-10-3
5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Guidance literature:: With pyridine; In dichloromethane; at 0 - 25 ℃;
DOI:10.1002/1521-3765(20020802)8:15<3327::AID-CHEM3327>3.0.CO;2-F

Reference yield: 70.0%

: 428861-09-0,479678-70-1
6-methoxy-5,6-benzo-2,2'-biphenol

: 428861-10-3
5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Guidance literature:: With pyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at 0 - 20 ℃; for 12h;

Reference yield:

: 2033-42-3
1-iodo-2-hydroxynaphthalene

: 428861-10-3
5',6'-benzo-6-methoxy-2,2'-biphenol bis-triflate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 85 percent / diethyl azodicarboxylate; PPh₃ / tetrahydrofuran / 20 °C

2.1: 75 percent / diethyl azodicarboxylate; PPh₃ / tetrahydrofuran / 20 °C

3.1: nBuLi / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: CuCN / tetrahydrofuran; hexane / 2 h / -78 °C

3.3: 50 percent / O₂ / tetrahydrofuran; hexane / -78 °C

4.1: 78 percent / boron tribromide / CH₂Cl₂ / 3 h / -50 °C

5.1: 70 percent / pyridine / CH₂Cl₂ / 0 - 25 °C

With pyridine; n-butyllithium; boron tribromide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1002/1521-3765(20020802)8:15<3327::AID-CHEM3327>3.0.CO;2-F