N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine

Base Information

• Chemical Name: N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine
• CAS No.: 74282-73-8
• Molecular Formula: C₄₂H₅₆N₂S₂
• Molecular Weight: 653.052
• Mol file: 74282-73-8.mol

Synonyms:N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine

Chemical Property of N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine

There total 3 articles about N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

N-(3,5-Di-tert-butylphenyl)-4-methylbenzenesulfenamide (74282-60-3) → N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine (74282-73-8)

Guidance literature:

With potassium carbonate; lead dioxide; In benzene; for 0.25h; Ambient temperature;

DOI:10.1021/jo01307a028

Reference yield:

p-methylbenzenesulfenyl chloride (933-00-6) → N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine (74282-73-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 62 percent / triethylamine / diethyl ether / 1 h / 0 - 5 °C

2: 54 percent / lead dioxide, potassium carbonate / benzene / 0.25 h / Ambient temperature

With potassium carbonate; lead dioxide; triethylamine; In diethyl ether; benzene;

DOI:10.1021/jo01307a028

Reference yield:

N-(4-Methylphenylthio)-3,5-di-tert-butylphenylaminyl (74282-68-1) → N,N'-Bis(3,5-di-tert-butylphenyl)-N,N'-bis<(4-methylphenyl)thio>hydrazine (74282-73-8)

Guidance literature:

In benzene; at 27 ℃; Equilibrium constant;

DOI:10.1021/jo01307a028

upstream raw materials:

N-(4-Methylphenylthio)-3,5-di-tert-butylphenylaminyl

N-(3,5-Di-tert-butylphenyl)-4-methylbenzenesulfenamide

p-methylbenzenesulfenyl chloride

Downstream raw materials:

N-(4-Methylphenylthio)-3,5-di-tert-butylphenylaminyl

α,α'-Bis-p-phenylenedimalononitrile