(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

Base Information

Chemical Name:(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate
CAS No.:864875-49-0
Molecular Formula:C₂₂H₂₂Cl₃NO₇
Molecular Weight:518.778
Hs Code.:

Synonyms:(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

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Chemical Property of (2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

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Technology Process of (2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

There total 10 articles about (2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 864875-47-8
(2S,3R,4R,5R,6R)-5-azido-2-(iodomethyl)-6-phenoxytetrahydro-2H-pyran-3,4-diol

: 864875-49-0
(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / pyridine

2: H₂; Et₃N / Pd/C / ethanol

3: pyridine

With pyridine; hydrogen; triethylamine; palladium on activated charcoal; In ethanol;
DOI:10.1002/anie.200500892

Reference yield:

: 864875-46-7
(2R,3R,4R,5R,6R)-5-azido-2-(hydroxymethyl)-6-phenoxytetrahydro-2H-pyran-3,4-diol

: 864875-49-0
(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / pyridine

2: 91 percent / NaI; n-Bu₄NI / 1,2-dimethoxy-ethane

3: 93 percent / pyridine

4: H₂; Et₃N / Pd/C / ethanol

5: pyridine

With pyridine; hydrogen; tetra-(n-butyl)ammonium iodide; triethylamine; sodium iodide; palladium on activated charcoal; In 1,2-dimethoxyethane; ethanol;
DOI:10.1002/anie.200500892

Reference yield:

: 864875-48-9
(2R,3R,4R,5R,6S)-3-azido-5-hydroxy-6-(iodomethyl)-2-phenoxytetrahydro-2H-pyran-4-yl benzoate

: 864875-49-0
(2R,3S,4R,5R,6R)-3-hydroxy-2-methyl-6-phenoxy-5-((2,2,2-trichloroethoxy)carbonylamino)tetrahydro-2H-pyran-4-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: H₂; Et₃N / Pd/C / ethanol

2: pyridine

With pyridine; hydrogen; triethylamine; palladium on activated charcoal; In ethanol;
DOI:10.1002/anie.200500892