dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

Base Information

Chemical Name:dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate
CAS No.:1453855-79-2
Molecular Formula:C₂₆H₂₈O₁₂
Molecular Weight:532.501
Hs Code.:

Synonyms:dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

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Chemical Property of dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

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Technology Process of dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

There total 5 articles about dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 177735-55-6
(3,5-bis(methoxycarbonyl)phenyl)boronic acid

: 1453855-49-6
((2R,3S,4R,5S,6R)-3-acetoxy-4,5-dihydroxy-6-(3-hydroxyphenyl)tetrahydro-2H-pyran-2-yl)methyl acetate

: 1453855-79-2
dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

Guidance literature:: With 2,6-dimethylpyridine; copper diacetate; In dichloromethane; at 20 ℃; for 72h; Molecular sieve;

Reference yield:

: 1453855-65-6
[(2R,3S,4R,5S,6R)-3-acetoxy-6-[3-[tert-butyl(dimethyl)silyl]oxyphenyl]-4,5-dihydroxytetrahydropyran-2-yl]methyl acetate

: 1453855-79-2
dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

Guidance literature:: Multi-step reaction with 2 steps

1: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h

2: copper diacetate; 2,6-dimethylpyridine / dichloromethane / 72 h / 20 °C / Molecular sieve

With 2,6-dimethylpyridine; tetrabutyl ammonium fluoride; copper diacetate; acetic acid; In tetrahydrofuran; dichloromethane;

Reference yield:

: 2873-29-2
D-glucal triacetate

: 1453855-79-2
dimethyl 5-(3-((2R,3S,4R,5S,6R)-5-acetoxy-6-(acetoxymethyl)-3,4-dihydroxytetrahydro-2H-pyran-2-yl)phenoxy)isophthalate

Guidance literature:: Multi-step reaction with 4 steps

1: palladium diacetate / acetonitrile / 20 °C

2: 4-methylmorpholine N-oxide; methanesulfonamide; osmium(VIII) oxide; 2,6-dimethylpyridine / water; tert-butyl alcohol / 20 °C

3: acetic acid; tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h

4: copper diacetate; 2,6-dimethylpyridine / dichloromethane / 72 h / 20 °C / Molecular sieve

With 2,6-dimethylpyridine; osmium(VIII) oxide; methanesulfonamide; tetrabutyl ammonium fluoride; copper diacetate; palladium diacetate; acetic acid; 4-methylmorpholine N-oxide; In tetrahydrofuran; dichloromethane; water; acetonitrile; tert-butyl alcohol;