2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

Base Information

Chemical Name:2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone
CAS No.:252577-53-0
Molecular Formula:C₂₆H₃₁NO₂S
Molecular Weight:421.604
Hs Code.:

Synonyms:2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

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Chemical Property of 2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

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Technology Process of 2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

There total 1 articles about 2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 106-51-4
p-benzoquinone

: 252577-49-4
((1R,2S,4aS,8aS)-1,2,4a,5-Tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-yl)-acetic acid 2-thioxo-2H-pyridin-1-yl ester

: 252577-53-0
2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

Guidance literature:: In dichloromethane; at 0 ℃; for 2h; UV-irradiation;
DOI:10.1002/(SICI)1521-3773(19991018)38:20<3089::AID-ANIE3089>3.0.CO;2-W

Reference yield: 84.0%

: 252577-53-0
2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

: 55303-98-5
avarol

Guidance literature:: With nickel; In dichloromethane; at 45 ℃; for 0.166667h;
DOI:10.1002/(SICI)1521-3773(19991018)38:20<3089::AID-ANIE3089>3.0.CO;2-W

Reference yield: 61.0%

: 124-41-4
sodium methylate

: 252577-53-0
2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

: 5-Methoxy-2-(pyridin-3-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

: 5-Methoxy-3-(pyridin-3-ylsulfanyl)-2-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone

Guidance literature:: sodium methylate; 2-(Pyridin-2-ylsulfanyl)-3-((1R,2S,4aS,8aS)-1,2,4a,5-tetramethyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-1-ylmethyl)-[1,4]benzoquinone; With methanol; In tetrahydrofuran; at -20 ℃; for 2h;

With ammonium chloride; In ethyl acetate; at 25 ℃; for 1h;
DOI:10.1021/ja027517q