methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Base Information

Chemical Name:methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside
CAS No.:114827-94-0
Molecular Formula:C₂₈H₃₅NO₈
Molecular Weight:513.588
Hs Code.:

Synonyms:methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Suppliers and Price of methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

There total 18 articles about methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 98-88-4
benzoyl chloride

: 114827-92-8
methyl 3-acetyl-2,3-dideoxy-2-(2,4-dimethoxybenzylamino)-5,6-O-isopropylidene-α-D-mannofuranoside

: 114827-94-0
methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: With triethylamine; In tetrahydrofuran;
DOI:10.1246/cl.1987.1403

Reference yield:

: 127950-24-7
(1R,2S,4S,5S)-2-<(1R)-1,2-dihydroxyethyl>-6-(2,4-dimethoxybenzyl)-4-methoxy-3-oxa-6-azabicyclo<3.2.0>heptan-7-one

: 114827-94-0
methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / pyridinium p-toluenesulfonate / dimethylformamide / 18 h / Ambient temperature

2: 76 percent / diethyl ether; tetrahydrofuran / 0.25 h / -78 °C

3: 74 percent / Et₃N / tetrahydrofuran / Ambient temperature

With triethylamine; pyridinium p-toluenesulfonate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.62.3950

Reference yield:

: (1R,3S,4S,5R,8R)-4-(2,4-dimethoxybenzylamino)-8-hydroxymethyl-3-methoxy-2,7-dioxabicyclo<3.3.0>octan-6-one

: 114827-94-0
methyl 3-acetyl-2,3-dideoxy-2-(N-2,4-dimethoxybenzylbenzamido)-5,6-O-isopropylidene-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 67 percent / MeMgBr / tetrahydrofuran / 0.5 h

2: 92 percent / pyridinium p-toluenesulfonate / dimethylformamide / 18 h / Ambient temperature

3: 76 percent / diethyl ether; tetrahydrofuran / 0.25 h / -78 °C

4: 74 percent / Et₃N / tetrahydrofuran / Ambient temperature

With methylmagnesium bromide; triethylamine; pyridinium p-toluenesulfonate; In tetrahydrofuran; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1246/bcsj.62.3950