methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

Base Information

Chemical Name:methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate
CAS No.:866611-76-9
Molecular Formula:C₃₇H₅₈N₆O₁₇
Molecular Weight:858.898
Hs Code.:

methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

Synonyms:methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

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Chemical Property of methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

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Technology Process of methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

There total 1 articles about methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 866611-74-7
methyl 1-(4-(2-(1-(1,4,7,10-tetraazacyclododecyl))ethylcarbamoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

: 105-36-2
ethyl bromoacetate

: 866611-76-9
methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

Guidance literature:: With potassium carbonate; In acetone; at 20 ℃; for 48h;

Reference yield:

: 866611-76-9
methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

: gadolinium(III) chloride

: gadolinium (III) 1-(4-(2-(1-(4,7,10-tris-carboxymethyl-(1,4,7,10-tetraazacyclododecyl)))-ethylcarbamoyloxymethyl)-2-nitrophenyl)-β-D-glucopyranuronate

Guidance literature:: methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate; With sodium hydroxide; water; at 0 ℃; for 1.26667h;

With hydrogenchloride; In water; pH=6.5;

gadolinium(III) chloride; With methyl 1-(4-(2-hydroxyethylcarbamoyloxymethyl)-2-nitrophenyl)-2,3,4-tri-O-acetyl-β-D-glucopyronuronate; In water; at 0 - 20 ℃; for 72h; pH=5.5 - 6.5;

Reference yield:

: 866611-76-9
methyl-1-(4-(2-(1-(4,7,10-trisethylcarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

: 10025-76-0
europium(III) chloride

: europium(III)-1-(4-(2-(1-(4,7,10-triscarboxymethyl-(1,4,7,10-tetraazacyclododecyl)))ethylcarbomoyloxymethyl)-2-nitrophenyl)-β-D-glucopyronuronate

Guidance literature:: With hydrogenchloride; sodium hydroxide; In water; to soln. ligand in H2O 1 N NaOH was added at 0°C, soln. was srirred for 75 min, pH was brought to 6.5 with 0.1 N HCl, EuCl3 was added in H2O (pH=6.5), soln. was warmed to room temp. while stirring and pH=6-6.5, after 3 days, pH was brought to 8.2; mixt. was centrifuged to removed excess Gd(OH)3, trace solids were removed by filtration through nylon filter,soln. was lyophilized, solid was dissolved in water and purified by preparative HPLC; elem. anal.;
DOI:10.1021/ja042162r