Technology Process of 2,2'-dibromo-4,4'-dimethoxydiphenylamine
There total 3 articles about 2,2'-dibromo-4,4'-dimethoxydiphenylamine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate; benzyltrimethylazanium tribroman-2-uide;
In
methanol; dichloromethane;
at 20 ℃;
DOI:10.1002/anie.200390244
- Guidance literature:
-
Multi-step reaction with 2 steps
1: palladium diacetate; 1,1'-bis-(diphenylphosphino)ferrocene; sodium tert-pentoxide / toluene / 36 h / Glovebox; Inert atmosphere; Reflux
2: N-Bromosuccinimide / dichloromethane / 24 h / Inert atmosphere
With
1,1'-bis-(diphenylphosphino)ferrocene; N-Bromosuccinimide; palladium diacetate; sodium tert-pentoxide;
In
dichloromethane; toluene;
1: |Buchwald-Hartwig Coupling;
DOI:10.1021/ic503062w
- Guidance literature:
-
Multi-step reaction with 2 steps
1: palladium diacetate; 1,1'-bis-(diphenylphosphino)ferrocene; sodium tert-pentoxide / toluene / 36 h / Glovebox; Inert atmosphere; Reflux
2: N-Bromosuccinimide / dichloromethane / 24 h / Inert atmosphere
With
1,1'-bis-(diphenylphosphino)ferrocene; N-Bromosuccinimide; palladium diacetate; sodium tert-pentoxide;
In
dichloromethane; toluene;
1: |Buchwald-Hartwig Coupling;
DOI:10.1021/ic503062w
