C₆₄H₁₀₂O₁₃Si

Base Information

Chemical Name:C₆₄H₁₀₂O₁₃Si
CAS No.:1325710-83-5
Molecular Formula:C₆₄H₁₀₂O₁₃Si
Molecular Weight:1107.59
Hs Code.:

C<sub>64</sub>H<sub>102</sub>O<sub>13</sub>Si

Synonyms:C₆₄H₁₀₂O₁₃Si

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Chemical Property of C₆₄H₁₀₂O₁₃Si

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Technology Process of C₆₄H₁₀₂O₁₃Si

There total 31 articles about C₆₄H₁₀₂O₁₃Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 1325710-82-4
C₂₈H₅₀O₄Si

: 1325710-77-7
C₃₈H₅₆O₉

: 1325710-83-5
C₆₄H₁₀₂O₁₃Si

Guidance literature:: With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 20 ℃; for 14h; Inert atmosphere;
DOI:10.1021/ol201920j

Reference yield:

: 403696-81-1
5-(triisopropylsilyl)-4-pentyn-1-al

: 1325710-83-5
C₆₄H₁₀₂O₁₃Si

Guidance literature:: Multi-step reaction with 12 steps

1.1: chromium dichloride / tetrahydrofuran / 0 °C

2.1: dimethyl zinc(II); tert.-butyl lithium / tetrahydrofuran; n-heptane; pentane / 1.75 h / -70 °C / Inert atmosphere

2.2: 3 h / -70 °C / Inert atmosphere

3.1: pyridinium p-toluenesulfonate / tetrahydrofuran; methanol

4.1: pyridinium p-toluenesulfonate

5.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 4 h / Reflux; Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 0 °C

7.1: quinoline; hydrogen / hexane; ethyl acetate / 1.5 h

8.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.25 h / 0 °C

9.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 °C

9.2: 2 h / 0 °C

10.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 11 h

11.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 2 h / 20 °C

12.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 14 h / 20 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; quinoline; chromium dichloride; Hoveyda-Grubbs catalyst second generation; tetrabutyl ammonium fluoride; hydrogen; dimethyl zinc(II); tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; hexane; n-heptane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; mineral oil; pentane; 2.2: Felkin-Anh addition;
DOI:10.1021/ol201920j

Reference yield:

: C₁₇H₃₄O₄Si

: 1325710-83-5
C₆₄H₁₀₂O₁₃Si

Guidance literature:: Multi-step reaction with 13 steps

1.1: 1H-imidazole; dmap / dichloromethane / 2 h / 20 °C

2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1.25 h / -70 °C

2.2: 2 h / -70 - 20 °C

3.1: dimethyl zinc(II); tert.-butyl lithium / tetrahydrofuran; n-heptane; pentane / 1.75 h / -70 °C / Inert atmosphere

3.2: 3 h / -70 °C / Inert atmosphere

4.1: pyridinium p-toluenesulfonate / tetrahydrofuran; methanol

5.1: pyridinium p-toluenesulfonate

6.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 4 h / Reflux; Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 0 °C

8.1: quinoline; hydrogen / hexane; ethyl acetate / 1.5 h

9.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.25 h / 0 °C

10.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 °C

10.2: 2 h / 0 °C

11.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 11 h

12.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 2 h / 20 °C

13.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 14 h / 20 °C / Inert atmosphere

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; quinoline; dmap; Hoveyda-Grubbs catalyst second generation; oxalyl dichloride; tetrabutyl ammonium fluoride; hydrogen; dimethyl zinc(II); tert.-butyl lithium; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; hexane; n-heptane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; mineral oil; pentane; 2.1: Swern oxidation / 2.2: Swern oxidation / 3.2: Felkin-Anh addition;
DOI:10.1021/ol201920j