Fe(CO)3{η3:η1-diphenylketene}

Base Information

• Chemical Name: Fe(CO)3{η3:η1-diphenylketene}
• CAS No.: 83417-55-4
• Molecular Formula: C₁₇H₁₀FeO₄
• Molecular Weight: 334.111
• Mol file: 83417-55-4.mol

Synonyms:Fe(CO)3{η3:η1-diphenylketene}

Chemical Property of Fe(CO)3{η3:η1-diphenylketene}

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Fe(CO)3{η3:η1-diphenylketene}

There total 2 articles about Fe(CO)3{η3:η1-diphenylketene} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + diphenyl ketene (525-06-4) → Fe(CO)3{η3:η1-diphenylketene} (83417-55-4)

Guidance literature:

In diethyl ether; byproducts: CO; Irradiation (UV/VIS); soln. of Fe(CO)5 and diphenylketene in Et2O was irradiated with mercury high-pressure lamp at 15°C;

Reference yield: 38.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + diphenyl ketene (525-06-4) → [μ-C=C(C6H5)2][Fe(CO)4]2 + Fe(CO)3{η3:η1-diphenylketene} (83417-55-4)

Guidance literature:

In diethyl ether; byproducts: CO; Irradiation (UV/VIS); under stirring for 6.5 h, filtration, filtrate evapd. in vac.; residue chromy. on SiO2 at 15°C elution first n-pentane then n-pentane/benzene (2/1), evapn. of eluate, residue take up in n-pentane (-50°C), recrystn., elem. anal.;

DOI:10.1016/S0022-328X(00)82964-2

Reference yield: 24.0%

Fe(CO)3{η3:η1-diphenylketene} (83417-55-4) + ethene (74-85-1) → tricarbonyl[η2:η2-1,1-diphenylpropene(1)]iron + C13H10*Fe2*6CO=(C13H10)Fe2(CO)6

Guidance literature:

In hexane; a soln. of Fe-complex in hexane was heated under reflux under CH2=CH2 atmosphere for 60 min; evapd. in vacuo, residue chromd. on a SiO2 column (eluent hexane for mononuclear complex followed by petroleum ether-benzene for binuclear one), hexane soln. was evapd., residue recrystd. from 1/1 petroleum ether/Et2O at -35°C; elem. anal.;

DOI:10.1016/S0022-328X(00)81215-2

upstream raw materials:

iron pentacarbonyl

diphenyl ketene