((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

Base Information

Chemical Name:((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane
CAS No.:206125-07-7
Molecular Formula:C₂₁H₃₄O₄Si
Molecular Weight:378.584
Hs Code.:

Synonyms:((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

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Chemical Property of ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

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Technology Process of ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

There total 1 articles about ((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 13154-24-0
triisopropylsilyl chloride

: 61134-24-5
Benzyl 2,3-anhydro-α-D-ribopyranoside

: 206125-07-7
((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 40 ℃; for 4h;
DOI:10.1016/S0040-4020(98)00120-3

Reference yield: 48.0%

: 917-54-4
methyllithium

: 206125-07-7
((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

: (2S,3R,4R,5S)-2-Benzyloxy-4-methyl-5-triisopropylsilanyloxy-tetrahydro-pyran-3-ol

: 206124-71-2
(2S,3S,4S,5R)-2-Benzyloxy-3-methyl-5-triisopropylsilanyloxy-tetrahydro-pyran-4-ol

Guidance literature:: With trimethylaluminum; In diethyl ether; hexane; for 4h; Heating;
DOI:10.1016/S0040-4020(98)00120-3

Reference yield:

: 206125-07-7
((1R,2S,5R,6S)-2-Benzyloxy-3,7-dioxa-bicyclo[4.1.0]hept-5-yloxy)-triisopropyl-silane

: (2R,3S,4S)-5-Benzyloxy-4-methyl-hexane-1,2,3-triol

Guidance literature:: Multi-step reaction with 3 steps

1: 48 percent / Me₃Al / diethyl ether; hexane / 4 h / Heating

2: 80 percent / Me₂AlCl / hexane / 0.5 h / 69 °C

3: TBAF / tetrahydrofuran / 4 h / Ambient temperature

With tetrabutyl ammonium fluoride; trimethylaluminum; dimethylaluminum chloride; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/S0040-4020(98)00120-3