N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Base Information

Chemical Name:N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine
CAS No.:1158841-79-2
Molecular Formula:C₄₃H₃₁N₃
Molecular Weight:589.739
Hs Code.:

Synonyms:N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Suppliers and Price of N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

There total 2 articles about N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1146340-38-6
1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole

: 202831-65-0
(4'-bromobiphenyl-4-yl)-diphenylamine

: 1158841-79-2
N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In water; toluene; at 110 ℃; Inert atmosphere; Schlenk technique;
DOI:10.1039/c9cp06466d

Reference yield:

: 2620-76-0
2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

: 1158841-79-2
N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

Guidance literature:: Multi-step reaction with 2 steps

1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / dimethyl sulfoxide / 24 h / 80 °C / Inert atmosphere

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetraethylammonium hydroxide / toluene; water / 18 h / 90 °C

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; tetraethylammonium hydroxide; In water; dimethyl sulfoxide; toluene; 2: |Suzuki Coupling;
DOI:10.1039/c2jm34462a

Reference yield: 25.0%

: iridium(III) chloride monohydrate

: 1158841-79-2
N,N-diphenyl-4-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1-terphenyl]-4-amine

: 123-54-6,81235-32-7
acetylacetone

: C₉₁H₇₁IrN₆O₂

Guidance literature:: iridium(III) chloride monohydrate; N,N-diphenyl-4"-(1-phenyl-1H-benzo[d]imidazol-2-yl)-[1,1':4',1"-terphenyl]-4-amine; In 2-ethoxy-ethanol; water; for 24h; Inert atmosphere; Reflux;

acetylacetone; With sodium carbonate; In 2-ethoxy-ethanol; Inert atmosphere; Reflux;
DOI:10.1039/c2jm34462a