Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)

Base Information

• Chemical Name: Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)
• CAS No.: 199169-92-1
• Molecular Formula: C₃₆H₄₉ClSn
• Molecular Weight: 635.948
• Mol file: 199169-92-1.mol

Synonyms:Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)

Chemical Property of Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)

There total 1 articles about Sn(Cl)(C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tin(ll) chloride + (Et2O)LiC6H3-2,6-(C6H2-2,4,6-(i-Pr)3)2 → [Sn(μ-Cl)(C6H3-2,6-(C6H2-2,4,6-i-Pr3)2)]2 + Sn(Cl)(C6H3-2,6-(C6H2-2,4,6-i-Pr3)2) (199169-92-1)

Guidance literature:

In diethyl ether; soln. of Et2O*LiC36H49 in diethyl ether added dropwise to stirred suspn.of SnCl2 in Et2O with cooling in an ice bath; soln. warmed to room temp . and stirred for 15 h; solvent removed and residue extracted with hexane and filtered; products sepd. after several recrystallizations from hexane under reduced pressure and approx. -20°C;

DOI:10.1016/S0277-5387(00)00661-6

Reference yield: 98.0%

Sn(Cl)(C6H3-2,6-(C6H2-2,4,6-i-Pr3)2) (199169-92-1) + (2-methylallyl)magnesium bromide (33324-92-4) → 2,6-(2,4,6-triisopropylphenyl)2C6H3SnC4H7

Guidance literature:

In hexane; benzene; at -40 - 20 ℃; for 3.5h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.8b00766

Reference yield: 97.0%

Sn(Cl)(C6H3-2,6-(C6H2-2,4,6-i-Pr3)2) (199169-92-1) + allylmagnesium bromide (2622-05-1) → (2,4,6-triisopropylphenyl)2C6H3SnC3H5

Guidance literature:

In 2-methyltetrahydrofuran; hexane; benzene; at -40 ℃; for 3h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/anie.201500386

Downstream raw materials:

Sn(Sn(Ph)2C₆H₃-2,6-(C₆H₂-2,4,6-i-Pr₃)2)2

2,6-Trip₂H₃C₆Sn-Sn(Me)2C₆H₃-2,6-Trip₂

Cr(η5-C5H5)(CO)3SnC6H3-2,6-Trip2

(C₆H₃-2,6(C₆H₂-2,4,6-Pr(i)3)2)SnSn(C₆H₃-2,6(C₆H₂-2,4,6-Pr(i)3)2)