tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

Base Information

Chemical Name:tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate
CAS No.:1313189-49-9
Molecular Formula:C₅₆H₆₀F₇NO₆S₂Si
Molecular Weight:1068.3
Hs Code.:

tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

Synonyms:tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

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Chemical Property of tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

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Technology Process of tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

There total 10 articles about tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29421-92-9
4-bromo-2-methylthiophene

: C₅₁H₆₁NO₆S₂Si

: 1313189-49-9
tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

Guidance literature:: Multi-step reaction with 5 steps

1.1: n-butyllithium / tetrahydrofuran; hexane; toluene / 0.5 h / -78 °C / Inert atmosphere

1.2: 0.05 h / -78 °C / Inert atmosphere

1.3: 1 h / -78 °C / Inert atmosphere

2.1: 1H-imidazole / N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

3.1: bromine; potassium acetate; acetic acid / 0 - 20 °C / Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

4.2: Inert atmosphere; Heating

4.3: 18 h / 40 °C / Inert atmosphere

5.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

5.2: 1 h / -78 °C / Inert atmosphere

With 1H-imidazole; n-butyllithium; bromine; potassium acetate; acetic acid; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/ejoc.201100166

Reference yield:

: 559-40-0
octaperfluorocyclopentene

: 1313189-48-8
tert-butyl N-[2-[4-[4'-bromo-3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

: C₅₁H₆₁NO₆S₂Si

: 1313189-49-9
tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

Guidance literature:: tert-butyl N-[2-[4-[4'-bromo-3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

octaperfluorocyclopentene; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;
DOI:10.1002/ejoc.201100166

Reference yield:

: 1313189-44-4
tert-butyl N-[3-(tert-butyldiphenylsilyloxy)propyl]-N-[2-[4-(thiophen-2-yl)phenoxy]ethyl]carbamate

: C₅₁H₆₁NO₆S₂Si

: 1313189-49-9
tert-butyl N-[2-[4-[3'-(2-tert-butyldiphenylsilyloxy)ethyl-5'-methyl-4'-(heptafluorocyclopent-1-enyl)[2,2']bithiophen-5-yl]phenoxy]ethyl]-N-[3-(4-methoxybenzyloxy)propyl]carbamate

Guidance literature:: Multi-step reaction with 5 steps

1.1: potassium acetate; Iodine monochloride; acetic acid / 0 - 50 °C / Inert atmosphere

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

3.1: potassium hydride / tetrahydrofuran; mineral oil / 0.33 h / 0 °C / Inert atmosphere

3.2: 0 - 20 °C / Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

4.2: Inert atmosphere; Heating

4.3: 18 h / 40 °C / Inert atmosphere

5.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

5.2: 1 h / -78 °C / Inert atmosphere

With n-butyllithium; tetrabutyl ammonium fluoride; potassium acetate; Iodine monochloride; potassium hydride; acetic acid; In tetrahydrofuran; hexane; mineral oil;
DOI:10.1002/ejoc.201100166