Rh(OC₆H₅)(ttp)

Base Information

Chemical Name:Rh(OC₆H₅)(ttp)
CAS No.:118657-58-2
Molecular Formula:C₄₂H₄₂OP₃Rh
Molecular Weight:758.622
Hs Code.:

Synonyms:Rh(OC₆H₅)(ttp)

Suppliers and Price of Rh(OC₆H₅)(ttp)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Rh(OC₆H₅)(ttp)

Chemical Property:

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Technology Process of Rh(OC₆H₅)(ttp)

There total 1 articles about Rh(OC₆H₅)(ttp) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.8%

: 60166-13-4
{Rh(OC₆H₅)COD}2

: 34989-06-5
Bis<3-(diphenylphosphino)propyl>phenylphosphin

: 118657-58-2
Rh(OC₆H₅)(ttp)

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

Guidance literature:: In toluene; addn. of soln. of ttp to suspension of Rh-complex, stirring overnight ; all manipulations under inert atmosphere; evapn., addn. of hexane, collection of solid on Schlenck frit, washing with hexane (2 times), toluene and hexane, drying in vacuo, elem. anal.;
DOI:10.1021/om00105a013

Reference yield: 76.0%

: 118657-58-2
Rh(OC₆H₅)(ttp)

: 586-76-5
4-Bromobenzoic acid

: 118657-63-9
Rh(OC(O)C₆H₄Br)(ttp)

Guidance literature:: In diethyl ether; toluene; addn. of soln of bromobenzoic acid in ether to suspension of Rh-complex in toluene (formation of clear soln.), stirring for 2.5 h; all operations under inert atmosphere; evapn., addn. of hexane, collection of ppt. on a Schlenk frit, washing with hexane, drying in vacuo ; elem. anal.;
DOI:10.1021/om00105a013

Reference yield: 73.0%

: 118657-58-2
Rh(OC₆H₅)(ttp)

: 118682-18-1
Rh(SO₂OC₆H₅)(ttp).SO₂

Guidance literature:: With SO₂; In tetrahydrofuran; bubbling SO2 through soln. of Rh-complex for 1 h, react. under inert atmosphere; concn. in vacuo, addn. of cyclohexane, collection of pptd. solid on a Schlenk frit, washing with cyclohexane, drying in vacuo ; elem. anal.;
DOI:10.1021/om00105a013