acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

Base Information

Chemical Name:acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester
CAS No.:916991-72-5
Molecular Formula:C₅₀H₇₆O₇SSi₂
Molecular Weight:877.386
Hs Code.:

acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

Synonyms:acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

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Chemical Property of acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

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Technology Process of acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

There total 1 articles about acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 916991-68-9
(2R,4S,7S)-11-(tert-butyldimethylsilanyloxy)-3-(tert-butyldiphenylsilanyloxy)-7-hydroxy-5-(4-methoxybenzyloxy)-8,8-dimethyl-9-methyleneundecanethioic acid S-tert-butyl ester

: 108-24-7
acetic anhydride

: 916991-72-5
acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1016/j.tetlet.2006.09.094

Reference yield: 94.0%

: 916991-72-5
acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

: 916991-69-0
acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-hydroxyhexyl ester

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In phosphate buffer; dichloromethane; at 20 ℃; for 2h; pH=7.0;
DOI:10.1016/j.tetlet.2006.09.094

Reference yield:

: 916991-72-5
acetic acid (1S,3S,5R)-1-[4-(tert-butyldimethylsilanyloxy)-1,1-dimethyl-2-methylenebutyl]-5-(tert-butyldiphenylsilanyloxy)-6-(tert-butylsulfanylcarbonyl)-3-(4-methoxybenzyloxy)hexyl ester

: acetic acid (2S,4S,6S)-6-[(R)-2-(tert-butyldiphenylsilanyloxy)-3-(tert-butylsulfanylcarbonyl)propyl]-2-(2-hydroxyethyl)-2-methoxy-3,3-dimethyltetrahydropyran-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 94 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / CH₂Cl₂; aq. phosphate buffer / 2 h / 20 °C / pH 7.0

2.1: O₃ / CH₂Cl₂ / 0.08 h / -78 °C

2.2: 91 percent / Me₂S / 12 h

3.1: 99 percent / (+/-)-camphor-10-sulfonic acid / 1.25 h / 20 °C

With camphor-10-sulfonic acid; ozone; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In phosphate buffer; dichloromethane;
DOI:10.1016/j.tetlet.2006.09.094