TRANS-1-HEXENYLBORONIC ACID PINACOL EST&

Base Information

• Chemical Name: TRANS-1-HEXENYLBORONIC ACID PINACOL EST&
• CAS No.: 126688-97-9
• Molecular Formula: C12H23 B O2
• Molecular Weight: 210.124
• Mol file: 126688-97-9.mol

Synonyms:1,3,2-Dioxaborolane,2-(1-hexenyl)-4,4,5,5-tetramethyl-, (E)-; 1,3,2-Dioxaborolane, 2-(1E)-1-hexenyl-4,4,5,5-tetramethyl-(9CI); 2-((E)-Hex-1-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property of TRANS-1-HEXENYLBORONIC ACID PINACOL EST&

Chemical Property:

• Vapor Pressure: 0.157mmHg at 25°C
• Refractive Index: n20/D 1.443
• Boiling Point: 62-65 °C0.5-0.6 mm Hg
• Flash Point: 197 °F
• PSA: 18.46000
• Density: 0.875 g/mL at 25 °C
• LogP: 3.36420
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-1-Hexen-1-ylboronic acid pinacol ester 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRANS-1-HEXENYLBORONIC ACID PINACOL EST&

There total 1 articles about TRANS-1-HEXENYLBORONIC ACID PINACOL EST& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-hexene (592-41-6,25067-06-5) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (126688-97-9) + 4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane (83947-56-2) + 4,4,5,5-tetramethyl-2-(1-phenyl-ethyl)-[1,3,2]dioxaborolane (174090-36-9) + 4,4,5,5-tetramethyl-2-phenethyl-1,3,2-dioxaborolane (165904-22-3) + 2-hex-1-yl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (86308-26-1)

Guidance literature:

chloro(1,5-cyclooctadiene)rhodium(I) dimer; In toluene; pinacolborane and vinylarene were added to a mixt. of Rh-complex in toluene under Ar, the mixt. was stirred at room temp. for 4 h; diluted with toluene, washed with water, dried over MgSO4, evapd., distilled with Kugelrohr or chromy. on silica gel;

DOI:10.1246/bcsj.75.825

Reference yield: 92.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (126688-97-9) → ((1E,3E)-octa-1,3-dien-1-yl)benzene (39491-69-5)

Guidance literature:

With oxygen; sodium carbonate; palladium diacetate; In N,N-dimethyl acetamide; at 23 ℃; for 6h;

DOI:10.1021/ol0483192

Reference yield: 91.0%

benzyl allyl ether (14593-43-2) + 2-[(1E)-hex-1-en-1-yl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (126688-97-9) → (2E,4E)-nona-2,4-dienyloxymethyl-benzene

Guidance literature:

With oxygen; sodium carbonate; palladium diacetate; In N,N-dimethyl acetamide; at 23 ℃; for 6h;

DOI:10.1021/ol0483192

upstream raw materials:

styrene

1-hexene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

Downstream raw materials:

5-n-butyl-3-phenyl-Δ²-isoxazoline

(2E)-1-phenylhept-2-en-1-ol

N-benzyl-N-(1-phenylpropyl)hydroxylamine