86308-26-1

Usage

Uses

Used in Organic Synthesis:
HEXYLBORONIC ACID PINACOL ESTER is used as a reagent in organic synthesis for its ability to form carbon-carbon bonds through Suzuki-Miyaura cross-coupling reactions. This allows for the creation of complex organic molecules with ease.
Used in Pharmaceutical Industry:
HEXYLBORONIC ACID PINACOL ESTER is used as a key intermediate in the preparation of various pharmaceuticals. Its versatility and stability make it an ideal candidate for the synthesis of a wide range of medicinal compounds.
Used in Agrochemical Industry:
HEXYLBORONIC ACID PINACOL ESTER is also utilized in the agrochemical industry for the synthesis of various agrochemicals. Its ability to form carbon-carbon bonds and its stability contribute to the development of effective and reliable agrochemical products.
Used in Research and Development:
HEXYLBORONIC ACID PINACOL ESTER is employed in research and development settings as a valuable building block for the construction of diverse chemical compounds. Its properties make it an attractive option for exploring new chemical reactions and syntheses.

InChI:InChI=1/C12H25BO2/c1-6-7-8-9-10-13-14-11(2,3)12(4,5)15-13/h6-10H2,1-5H3

Upstream product

• 100-42-5 styrene 
• 592-41-6 1-hexene 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 591-50-4 iodobenzene 
• 110-53-2 1-Bromopentane 
• 73183-34-3 bis(pinacol)diborane 
• 111-25-1 1-bromo-hexane 

Downstream Products

• 111-27-3 hexan-1-ol 
• 111-71-7 heptanal 
• 18794-77-9 2-hexylthiophene 
• 1077-16-3 hexylbenzene 
• 16343-08-1 hexylboronic acid 
• 1138-02-9 1-(4-chlorophenyl)heptan-1-ol 
• 4197-73-3 2-Hexyl-benzochinon-(1,4) 
• 4197-72-2 2-hexylhydroquinone 
• 687-09-2 2,2,2-trifluoro-N-hexylacetamide 
• 1129-69-7 2-hexylpyridine 

Relevant academic research and scientific papers

Carbon-carbon bond activation by B(OMe)3/B2pin2-mediated fragmentation borylation

Selective carbon-carbon bond activation is important in chemical industry and fundamental organic synthesis, but remains challenging. In this study, non-polar unstrained Csp2-Csp3 and Csp2-Csp2 bond activation was achieved by B(OMe)3/B2pin2-mediated fragmentation borylation. Various indole derivatives underwent C2-regioselective C-C bond activation to afford two C-B bonds under transition-metal-free conditions. Preliminary mechanistic investigations suggested that C-B bond formation and C-C bond cleavage probably occurred in a concerted process. This new reaction mode will stimulate the development of reactions based on inert C-C bond activation. This journal is

Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides

Easy access: An unprecedented copper-catalyzed cross-coupling reaction of the title compounds with diboron reagents is described (see scheme; Ts=4-toluenesulfonyl). This reaction can be used to prepare both primary and secondary alkylboronic esters having diverse structures and functional groups. The resulting products would be difficult to access by other means. Copyright

Rhodium- and ruthenium-catalyzed dehydrogenative borylation of vinylarenes with pinacolborane: Stereoselective synthesis of vinylboronates

The treatment of pinacolborane (4,4,5,5-tetramethyl-1,3,2- dioxaborolane) with vinylarenes in the presence of a catalytic amount of phosphine-free di-μ-chlorobis(1,5- cyclooctadiene)dirhodium(I) [RhCl(cod)]2, through dehydrogenative borylation, provides the corresponding regio- and stereodefined (E)-2-arylethenylboronates in high yields. Also, a ruthenium complex prepared in situ from (1,5-cyclooctadiene)(1,3,5-cyclooctatriene)ruthenium(O) [Ru(cod)(cot)] and P(4CF3C6H4)3 showed considerable catalytic activity for dehydrogenative borylation.