Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

Base Information

• Chemical Name: Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate
• CAS No.: 130296-28-5
• Molecular Formula: C16H24F6RhSb
• Molecular Weight: 0
• Mol file: 130296-28-5.mol

Synonyms:Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

Chemical Property of Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

Chemical Property:

• Melting Point: 58-60 °C
• PSA: 0.00000
• LogP: 7.86680
• Storage Temp.: ?20°C
• Sensitive.: Air stable, moisture sensitiv

Purity/Quality:

98%Min ^*data from raw suppliers

Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Catalyst for:[3+2] CycloadditionPreparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysisC-C bond-forming hydrogenation

Technology Process of Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

There total 1 articles about Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

silver hexafluoroantimonate (26042-64-8) + di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → [Rh(cyclo-octa-1,5-diene)2][SbF6] (130296-28-5)

Guidance literature:

In dichloromethane; excess of AgSbF6, stirring for 1 h; volume reduction, pptn. on Et2O addn.;

DOI:10.1039/DT9940003069

Reference yield: 69.0%

[Rh(cyclo-octa-1,5-diene)2][SbF6] (130296-28-5) + chlorotriphenylphosphinegold(I) (14243-64-2) + [bis(triphenylphosphane)iminium]2[Ru5C(CO)14] → [Ru5RhC(CO)14(cyclo-octa-1,5-diene)(μ3-AuPh3)]

Guidance literature:

In dichloromethane; addn. of Au-complex to mixt. of Ru-cluster and excess of Rh-complex, stirring for 10 min; chromy. (Kieselgel 60, CH2Cl2/hexane=1:1), pptn. on volume reduction andhexane addn.; elem. anal.;

DOI:10.1039/DT9940003069

Reference yield: 64.0%

[Rh(cyclo-octa-1,5-diene)2][SbF6] (130296-28-5) + [bis(triphenylphosphane)iminium]2[Ru5C(CO)14] → [N(PPh3)2][Ru5RhC(CO)14(cyclo-octa-1,5-diene)]

Guidance literature:

In dichloromethane; addn. of excess Rh-complex to Ru-cluster; filtration (Celite), evapn.; elem. anal.;

DOI:10.1039/DT9940003069

upstream raw materials:

silver hexafluoroantimonate

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

cyclo-octa-1,5-diene

Downstream raw materials:

Os3Rh(μ-H)3(CO)10(η(4)-cycloocta-1,5-diene)

Refernces