4-(Ethoxycarbonyl)phenylzinc bromide

Base Information

Chemical Name:4-(Ethoxycarbonyl)phenylzinc bromide
CAS No.:131379-15-2
Molecular Formula:C9H9 Br O2 Zn
Molecular Weight:294.463
Hs Code.:
European Community (EC) Number:803-021-0
Mol file:131379-15-2.mol

Synonyms:131379-15-2;4-(ETHOXYCARBONYL)PHENYLZINC BROMIDE;bromozinc(1+);ethyl benzoate;4-(Ethoxycarbonyl)phenylzinc bromide, 0.50 M in THF;MFCD05664208;4-(Ethoxycarbonyl)phenylzinc bromide, 0.5M in THF

Suppliers and Price of 4-(Ethoxycarbonyl)phenylzinc bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4-(Ethoxycarbonyl)phenylzinc bromide solution 0.5 M in THF
50ml
$ 291.00

Rieke Metals
4-(Ethoxycarbonyl)phenylzincbromide
50mL
$ 474.00

Rieke Metals
4-(Ethoxycarbonyl)phenylzincbromide
100mL
$ 656.00

American Custom Chemicals Corporation
4-(ETHOXYCARBONYL)PHENYLZINC BROMIDE 95.00%
5MG
$ 496.16

Alfa Aesar
4-(Ethoxycarbonyl)phenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
50ml
$ 206.00

Total 15 raw suppliers

Chemical Property of 4-(Ethoxycarbonyl)phenylzinc bromide

Chemical Property:

Vapor Pressure:0.18mmHg at 25°C
Boiling Point:65 °C
Flash Point:1 °F
PSA：26.30000
Density:1.023 g/mL at 25 °C
LogP:2.50660
Storage Temp.:2-8°C
Sensitive.:Air Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:291.90773
Heavy Atom Count:13
Complexity:228

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-(Ethoxycarbonyl)phenylzinc bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,C
Statements: 11-14-19-34-40-37
Safety Statements: 16-26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C1=CC=[C-]C=C1.[Zn+]Br

Technology Process of 4-(Ethoxycarbonyl)phenylzinc bromide

There total 5 articles about 4-(Ethoxycarbonyl)phenylzinc bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 5798-75-4
Ethyl 4-bromobenzoate

: 7440-66-6
zinc

: 93-89-0,99341-95-4
benzoic acid ethyl ester

: 47230-38-6
diethyl biphenyl-4,4'-dicarboxylate

: 131379-15-2
(4-(ethoxycarbonyl)phenyl)zinc(ll) bromide

Guidance literature:: With trifluoroacetic acid; cobalt(II) bromide; zinc dibromide; In acetonitrile; the mixt. in CH3CN was stirred at room temp., then arylbromide was added, stirred at room temp.; GC analysis;
DOI:10.1021/ja0289494

Reference yield: 76.0%

: 5798-75-4
Ethyl 4-bromobenzoate

: 93-89-0,99341-95-4
benzoic acid ethyl ester

: 47230-38-6
diethyl biphenyl-4,4'-dicarboxylate

: 131379-15-2
(4-(ethoxycarbonyl)phenyl)zinc(ll) bromide

Guidance literature:: With Ethyl 4-bromobenzoate; trifluoroacetic acid; cobalt(II) bromide; zinc; In hexanedinitrile; acetonitrile; for 0.166667 - 0.5h;

Ethyl 4-bromobenzoate; With zinc dibromide; In hexanedinitrile; acetonitrile; Product distribution / selectivity;

Reference yield: 60.0%

: 5798-75-4
Ethyl 4-bromobenzoate

: 131379-15-2
(4-(ethoxycarbonyl)phenyl)zinc(ll) bromide

Guidance literature:: With trifluoroacetic acid; cobalt(II) bromide; zinc dibromide; zinc; In pyridine; acetonitrile; for 24h; Conversion of starting material;