Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)
CAS No.:131784-71-9
Molecular Formula:C10H17NO2
Molecular Weight:183.24748
Hs Code.:
Mol file:131784-71-9.mol

Synonyms:Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)

Suppliers and Price of Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

Melting Point:57-59 °C
Boiling Point:246.5±13.0 °C(Predicted)
PKA:11.51±0.46(Predicted)
PSA：41.82000
Density:0.948±0.06 g/cm3(Predicted)
LogP:2.80530

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI)

There total 3 articles about Carbamic acid, 1,3-pentadienyl-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 134078-61-8,157372-85-5
tert-butyl N-((Z)-2,4-pentadienyl)carbamate

: 134078-73-2,131784-71-9
tert-butyl N-((1E,3Z)-1,3-pentadienyl)carbamate

Guidance literature:: (naphthalene)Cr(CO)3; In acetone; for 4h; Ambient temperature;
DOI:10.1021/jo00014a051

Reference yield:

: 65899-52-7
sorbic azide

: 75-65-0
tert-butyl alcohol

: 141966-91-8,131784-71-9
tert-butyl ((1E,3E)-penta-1,3-dien-1-yl)carbamate

Guidance literature:: With 2,6-di-tert-butyl-4-methyl-phenol; In toluene; for 3h; Heating;
DOI:10.1021/ja060282o

Reference yield:

: 134078-60-7
tert-butyl N-((Z)-2,4-pentadienyl)-N-(p-toluenesulfonyl)carbamate

: 134078-73-2,131784-71-9
tert-butyl N-((1E,3Z)-1,3-pentadienyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / NaH₂PO₄, 5percent Na-Hg / methanol / 1 h / 0 °C

2: 94 percent / (naphthalene)Cr(CO)3 / acetone / 4 h / Ambient temperature

With sodium dihydrogenphosphate; sodium amalgam; (naphthalene)Cr(CO)3; In methanol; acetone;
DOI:10.1021/jo00014a051