[2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

Base Information Edit

Chemical Name:[2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane
CAS No.:133545-16-1
Molecular Formula:C₃₈H₃₂O₂P₂
Molecular Weight:582.618
Hs Code.:29319090
DSSTox Substance ID:DTXSID10928180
Nikkaji Number:J1.147.191I,J1.492.854E,J817.354K
Wikidata:Q72467783
Mol file:133545-16-1.mol

Synonyms:133545-16-1;133545-17-2;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine);(R)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine);(S)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine);[2-(2-diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane;MeO-BIPHEP;(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine);S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM;MFCD03095430;MeOBiphep;(R)-(+)-MeO-BIPHEP;(S)-(-)-MeO-BIPHEP;SL-A101-2;SCHEMBL301296;DTXSID10928180;Phosphine, (6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl)bis[diphenyl-;AKOS015851710;(R)-(+)-(6,6 inverted exclamation marka-Dimethoxybiphenyl-2,2 inverted exclamation marka-diyl)bis(diphenylphosphine);AS-65653;SY045597;SY069454;D72573;D94894;A888050;J-006395;J-006396;(s)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine);(6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphane);(R)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphane);[2'-(DIPHENYLPHOSPHANYL)-6,6'-DIMETHOXY-[1,1'-BIPHENYL]-2-YL]DIPHENYLPHOSPHANE;(R)-(+)-(6,6 inverted exclamation mark -Dimethoxybiphenyl-2,2 inverted exclamation mark -diyl)bis(diphenylphosphine);(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine), >=97%, optical purity ee: >=99%;(S)-(+)-(6,6 inverted exclamation mark -Dimethoxybiphenyl-2,2 inverted exclamation mark -diyl)bis(diphenylphosphine);(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine), >=97%, optical purity ee: >=99%;(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine), puriss., >=98.0% (sum of enantiomers, HPLC)

Suppliers and Price of [2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
500mg
$ 278.00

Strem Chemicals
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
100mg
$ 74.00

Strem Chemicals
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
10g
$ 3784.00

Strem Chemicals
(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP
2g
$ 946.00

Sigma-Aldrich
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99%
1g
$ 505.00

Sigma-Aldrich
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99%
500mg
$ 286.00

Sigma-Aldrich
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99%
5g
$ 1970.00

Sigma-Aldrich
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) ≥97%, optical purity ee: ≥99%
100mg
$ 82.20

BLDpharm
(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 98+%
100mg
$ 78.00

BLDpharm
(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 98+%
250mg
$ 148.00

Total 35 raw suppliers

Chemical Property of [2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane Edit

Chemical Property:

Melting Point:213-216ºC
Boiling Point:651.1ºC at 760 mmHg
Flash Point:438.5ºC
PSA：45.64000
LogP:6.88720
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:8.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:9
Exact Mass:582.18775425
Heavy Atom Count:42
Complexity:667

Purity/Quality:

97% ^*data from raw suppliers

(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=CC=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC
Uses Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Technology Process of [2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane

There total 28 articles about [2-(2-Diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%