(3,3-Difluorocycloprop-1-en-1-yl)benzene

Base Information

Chemical Name:(3,3-Difluorocycloprop-1-en-1-yl)benzene
CAS No.:138101-00-5
Molecular Formula:C9H6F2
Molecular Weight:152.143
Hs Code.:
DSSTox Substance ID:DTXSID60449976
Nikkaji Number:J2.750.016A
Wikidata:Q82269530
Mol file:138101-00-5.mol

Synonyms:138101-00-5;(3,3-Difluorocycloprop-1-en-1-yl)benzene;(3,3-difluorocyclopropen-1-yl)benzene;Benzene, (3,3-difluoro-1-cyclopropen-1-yl)- (9CI);starbld0018406;DTXSID60449976;FKPIRBZASXPNCD-UHFFFAOYSA-N;3,3-Difluoro-1-phenylcyclopropene;(3,3-Difluoro-1-cyclopropen-1-yl)benzene

Suppliers and Price of (3,3-Difluorocycloprop-1-en-1-yl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (3,3-Difluorocycloprop-1-en-1-yl)benzene

Chemical Property:

PSA：0.00000
LogP:2.71890
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:152.04375652
Heavy Atom Count:11
Complexity:188

Purity/Quality:: 99%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C2=CC2(F)F

Technology Process of (3,3-Difluorocycloprop-1-en-1-yl)benzene

There total 8 articles about (3,3-Difluorocycloprop-1-en-1-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 115262-01-6
[bromo(difluoro)methyl]-trimethyl-silane

: 536-74-3
phenylacetylene

: 138101-00-5
(3,3-difluorocycloprop-1-en-1-yl)benzene

Guidance literature:: With tetrabutylammomium bromide; In toluene; at 20 - 110 ℃; for 2h; Time; Temperature; Solvent; Inert atmosphere;
DOI:10.1002/anie.201306703

Reference yield: 92.0%

: 81290-20-2
(trifluoromethyl)trimethylsilane

: 536-74-3
phenylacetylene

: 138101-00-5
(3,3-difluorocycloprop-1-en-1-yl)benzene

Guidance literature:: phenylacetylene; With sodium iodide; In tetrahydrofuran; Inert atmosphere; Reflux;

(trifluoromethyl)trimethylsilane; In tetrahydrofuran; for 4h; Inert atmosphere; Reflux;
DOI:10.1002/ejoc.202100921

Reference yield: 79.0%

: 75-61-6
dibromodifluoromethane

: 536-74-3
phenylacetylene

: 138101-00-5
(3,3-difluorocycloprop-1-en-1-yl)benzene

Guidance literature:: With potassium fluoride; 18-crown-6 ether; triphenylphosphine; In 1,2-dimethoxyethane; at 25 ℃;
DOI:10.1016/S0040-4020(01)89734-9