1-Bromo-11-iodoundecane

Base Information

• Chemical Name: 1-Bromo-11-iodoundecane
• CAS No.: 139123-69-6
• Molecular Formula: C11H22BrI
• Molecular Weight: 361.104
• Mol file: 139123-69-6.mol

Synonyms:1-Bromo-11-iodoundecane

Chemical Property of 1-Bromo-11-iodoundecane

Chemical Property:

• PSA: 0.00000
• LogP: 5.32720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Bromo-11-iodoundecane

There total 2 articles about 1-Bromo-11-iodoundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromo-11-hydroxyundecane (1611-56-9) → 1,11-dibromoundecane (16696-65-4) + 1,11-diiodoundecane (24613-66-9) + 1-bromo-11-iodoundecane (139123-69-6)

Guidance literature:

1-Bromo-11-hydroxyundecane; With copper(II) bis(trifluoromethanesulfonate); diisopropyl-carbodiimide; at 20 ℃; for 1h;

With N-iodo-succinimide; In tetrahydrofuran; at 150 ℃; for 0.0833333h; microwave irradiation;

DOI:10.1016/j.tetlet.2003.09.024

Reference yield:

1-undecen-11-ylbromide (7766-50-9) → 1-bromo-11-iodoundecane (139123-69-6)

Guidance literature:

1-undecen-11-ylbromide; With triisobutylaluminum; bis-triphenylphosphine-palladium(II) chloride; In dichloromethane; at 25 ℃; for 1h;

With iodine; In dichloromethane;

DOI:10.1016/S0040-4039(00)02142-0

upstream raw materials:

1-undecen-11-ylbromide

1-Bromo-11-hydroxyundecane

Refernces

• 1、 Gagneur, Sebastien,Makabe, Hidefumi,Negishi, Ei-Ichi. "A novel hydrogen transfer hydroalumination of alkenes with triisobutylaluminum catalyzed by Pd and other late transition metal complexes". . p. 785 - 787. Retrieved 2007/10/03.