1,11-Diiodoundecane

Base Information

• Chemical Name: 1,11-Diiodoundecane
• CAS No.: 24613-66-9
• Molecular Formula: C11H22I2
• Molecular Weight: 408.105
• European Community (EC) Number: 669-083-4
• DSSTox Substance ID: DTXSID301315609
• Mol file: 24613-66-9.mol

Synonyms:1,11-diiodoundecane;24613-66-9;Undecane, 1,11-diiodo-;SCHEMBL6001947;DTXSID301315609;MFCD00034598;AKOS024432129;SY315954

Chemical Property of 1,11-Diiodoundecane

Chemical Property:

• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 407.98110
• Heavy Atom Count: 13
• Complexity: 74.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CCCCCI)CCCCCI

Technology Process of 1,11-Diiodoundecane

There total 1 articles about 1,11-Diiodoundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-Bromo-11-hydroxyundecane (1611-56-9) → 1,11-dibromoundecane (16696-65-4) + 1,11-diiodoundecane (24613-66-9) + 1-bromo-11-iodoundecane (139123-69-6)

Guidance literature:

1-Bromo-11-hydroxyundecane; With copper(II) bis(trifluoromethanesulfonate); diisopropyl-carbodiimide; at 20 ℃; for 1h;

With N-iodo-succinimide; In tetrahydrofuran; at 150 ℃; for 0.0833333h; microwave irradiation;

DOI:10.1016/j.tetlet.2003.09.024

Reference yield:

1,11-diiodoundecane (24613-66-9) → brassylic acid (505-52-2)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous alcohol

2: concentrated hydrochloric acid / 120 °C

With hydrogenchloride; ethanol;

DOI:10.1359/jbmr.2001.16.9.1651

Reference yield:

1,11-diiodoundecane (24613-66-9) + sodium phenoxide (139-02-6) → 1,11-diphenoxy-undecane (141620-04-4)

Guidance literature:

With ethanol;

DOI:10.1359/jbmr.2001.16.9.1651

upstream raw materials:

1-Bromo-11-hydroxyundecane

Downstream raw materials:

1,11-diphenoxy-undecane

brassylic acid

Refernces