2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE)

Base Information

Chemical Name:2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE)
CAS No.:139220-25-0
Molecular Formula:C₃₀H₃₅F₁₂MoNO₂
Molecular Weight:765.534
Hs Code.:
Mol file:139220-25-0.mol

Synonyms:SCHROCK'S CATALYST;2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE);2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI)BIS(HEXAFLUORO-T-BUTOXIDE);2,6-DIISOPROPYLPHENYLIMIDONEOPHYLIDENEB&;2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluorotert-butoxide);2,6-Diisopropylphenylimidoneophylidenemolybdenum(VI)bis(hexafluoro-t-butoxide)SCHROCK'SCATALYST

Suppliers and Price of 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST
500mg
$ 592.00

Strem Chemicals
[2,6-Bis(1-methylethyl)benzenaminato(2-)]bis(1,1,1,3,3,3-hexafluoro-2-methyl-2-propanolato-κO)(2-methyl-2-phenylpropylidene)-, (T-4) molybdenum, paraffin pellet
10pcs
$ 180.00

Strem Chemicals
2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST
100mg
$ 148.00

Strem Chemicals
[2,6-Bis(1-methylethyl)benzenaminato(2-)]bis(1,1,1,3,3,3-hexafluoro-2-methyl-2-propanolato-κO)(2-methyl-2-phenylpropylidene)-, (T-4) molybdenum, paraffin pellet
2pcs
$ 72.00

Strem Chemicals
2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST
2g
$ 1776.00

American Custom Chemicals Corporation
2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI) BIS(HEXAFLUORO-T-BUTOXIDE) 95.00%
2G
$ 1803.00

American Custom Chemicals Corporation
2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI) BIS(HEXAFLUORO-T-BUTOXIDE) 95.00%
500MG
$ 984.75

American Custom Chemicals Corporation
2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM(VI) BIS(HEXAFLUORO-T-BUTOXIDE) 95.00%
100MG
$ 669.44

Total 10 raw suppliers

Chemical Property of 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE)

Chemical Property:

PSA：30.82000
LogP:11.31470
Sensitive.:air sensitive, moisture sensitiv

Purity/Quality:

98%Min ^*data from raw suppliers

2,6-Diisopropylphenylimidoneophylidene molybdenum(VI) bis(hexafluoro-t-butoxide) SCHROCK'S CATALYST ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE)

There total 7 articles about 2,6-DIISOPROPYLPHENYLIMIDO NEOPHYLIDENEMOLYBDENUM BIS(HEXAFLUORO-T-BUTOXIDE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 645391-49-7
Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)

: 98171-13-2
1,1,1,3,3,3-hexafluoro-2-methylpropoxylithium

: 139220-25-0,149883-30-7,149883-29-4
bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum

Guidance literature:: In diethyl ether; under N2: addn. of LiOC(CH3)(CF3)2 to a cold (-30°C) soln. of Mo-compound in diethyl ether; warming to room temperature with stirring for 1 h; removing solvent in vac.;; extraction with pentane; filtration; removing solvent in vac.; recrystallization from pentane at -40°C; elem. anal.;;
DOI:10.1021/om00027a028

Reference yield:

: 149883-29-4,139220-25-0,149883-30-7
Mo(CHC(CH₃)2C₆H₅)(NC₆H₃(CH(CH₃)2)2)(OC(CH₃)(CF₃)2)2

: 149883-29-4,149883-30-7,139220-25-0
Mo{NC₆H₃(CH(CH₃)2)2}{CHC(CH₃)2C₆H₅}{OC(CH₃)(CF₃)2}2

Guidance literature:: In ⁽²⁾H₈-toluene; Irradiation (UV/VIS); photolysis (366 nm) for several h at -80°C; monitored by (1)-NMR; Kinetics;
DOI:10.1021/ja00045a056