1,4-Bis(DI-tert-butylphosphino)butane

Base Information

Chemical Name:1,4-Bis(DI-tert-butylphosphino)butane
CAS No.:150111-89-0
Molecular Formula:C20H44 P2
Molecular Weight:346.517
Hs Code.:
European Community (EC) Number:873-014-5
DSSTox Substance ID:DTXSID70473303
Nikkaji Number:J2.414.137C
Wikidata:Q72445558
Mol file:150111-89-0.mol

Synonyms:1,4-BIS(DI-TERT-BUTYLPHOSPHINO)BUTANE;150111-89-0;ditert-butyl(4-ditert-butylphosphanylbutyl)phosphane;Phosphine, 1,1'-(1,4-butanediyl)bis[1,1-bis(1,1-dimethylethyl)-;SCHEMBL294768;DTXSID70473303;AMY42143;1,4-Bis(di-t-butylphosphino)butane;MFCD01074568;FT-0710990;A884198

Suppliers and Price of 1,4-Bis(DI-tert-butylphosphino)butane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
1,4-Bis(di-tert-butylphosphino)butane 97%
1g
$ 950.00

American Custom Chemicals Corporation
1,4-BIS(DI-TERT-BUTYLPHOSPHINO)BUTANE 95.00%
5MG
$ 503.90

Total 22 raw suppliers

Chemical Property of 1,4-Bis(DI-tert-butylphosphino)butane

Chemical Property:

Boiling Point:394.9±25.0 °C(Predicted)
PSA：27.18000
LogP:7.92440
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:9
Exact Mass:346.29182540
Heavy Atom Count:22
Complexity:256

Purity/Quality:

97% ^*data from raw suppliers

1,4-Bis(di-tert-butylphosphino)butane 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)P(CCCCP(C(C)(C)C)C(C)(C)C)C(C)(C)C

Technology Process of 1,4-Bis(DI-tert-butylphosphino)butane

There total 4 articles about 1,4-Bis(DI-tert-butylphosphino)butane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 819-19-2
di-tert-butylphosphine

: 110-56-5
1,4-dichlorobutane

: 150111-89-0
1,4-bis(di-tert-butylphosphino)butane

Guidance literature:: di-tert-butylphosphine; With tert.-butyl lithium; In diethyl ether; hexane; at 0 ℃; for 0.166667h;

1,4-dichlorobutane; In diethyl ether; hexane; at 0 - 20 ℃; for 1.33333h;
DOI:10.1021/ma1013572

Reference yield: 73.0%

: 19966-86-0
lithium di-tert-butylphosphide

: 110-56-5
1,4-dichlorobutane

: 150111-89-0
1,4-bis(di-tert-butylphosphino)butane

Guidance literature:: In 1,4-dioxane; at 0 - 20 ℃;
DOI:10.1016/j.tetlet.2006.12.027

Reference yield: 48.0%

: 110-52-1
1,4-dibromo-butane

: di-tert-butylphosphine borane

: 150111-89-0
1,4-bis(di-tert-butylphosphino)butane

Guidance literature:: di-tert-butylphosphine borane; With n-butyllithium; In tetrahydrofuran; cyclohexane; at -78 - 20 ℃; for 1h;

1,4-dibromo-butane; In tetrahydrofuran; cyclohexane; at -78 - 20 ℃;

With pyrrolidine; at 50 ℃; for 16h;
DOI:10.1021/acs.organomet.5b00517