819-19-2Relevant articles and documents
On the compatibility of Ruthenium metathesis catalysts with secondary phosphines
Van Lierop, Bianca J.,Fogg, Deryn E.
, p. 7245 - 7248 (2013)
While attempts to incorporate secondary phosphine ligands into the first-generation Grubbs catalyst RuCl2(PR3) 2(=CHPh) (GI, R = Cy) were frustrated by decomposition (for HPCy 2) or bulk (for HPtBusu
Reactivity of diimido complexes of moybdenum and tungsten towards lithium derivatives of diphosphanes and triphosphanes
Grubba, Rafa?,Wi?niewska, Aleksandra,Ponikiewski, ?ukasz,Caporali, Maria,Peruzzini, Maurizio,Pikies, Jerzy
, p. 1811 - 1817 (2014/04/17)
The reaction of R2P-P(SiMe3)Li (R = tBu, iPr) with the diimido molybdenum complex [(ArN)2MoCl2·dme] (Ar = 2,6-iPr2C6H3; dme = 1,2-dimethoxyethane) yielded the side-on-coordinated
Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes
Wi?niewska, Aleksandra,?apczuk-Krygier, Agnieszka,Baranowska, Katarzyna,Chojnacki, Jaros?aw,Matern, Eberhard,Pikies, Jerzy,Grubba, Rafa?
, p. 45 - 48 (2013/08/25)
The reactions of R2P-P(SiMe3)Li (R = tBu, iPr, iPr2N) with [Cp2MCl 2] (M = Zr, Hf), [Cp*z.ast;CpZrCl2] and [CpZrCl 3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R 2P-P(SiMe3)Li can act as a building block for the formation of the P2 ligand and the R2P-P(P2) and R2P-P(P2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P- P(P2) and R2P-P(P2)P-PR2 ligands were established by X-ray studies.