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819-19-2

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819-19-2 Usage

Chemical Properties

colourless liquid

Uses

suzuki reaction

Check Digit Verification of cas no

The CAS Registry Mumber 819-19-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,1 and 9 respectively; the second part has 2 digits, 1 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 819-19:
(5*8)+(4*1)+(3*9)+(2*1)+(1*9)=82
82 % 10 = 2
So 819-19-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H19P/c1-7(2,3)9-8(4,5)6/h9H,1-6H3

819-19-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name DI-T-Butylphosphine

1.2 Other means of identification

Product number -
Other names ditert-butylphosphane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:819-19-2 SDS

819-19-2Relevant articles and documents

On the compatibility of Ruthenium metathesis catalysts with secondary phosphines

Van Lierop, Bianca J.,Fogg, Deryn E.

, p. 7245 - 7248 (2013)

While attempts to incorporate secondary phosphine ligands into the first-generation Grubbs catalyst RuCl2(PR3) 2(=CHPh) (GI, R = Cy) were frustrated by decomposition (for HPCy 2) or bulk (for HPtBusu

Reactivity of diimido complexes of moybdenum and tungsten towards lithium derivatives of diphosphanes and triphosphanes

Grubba, Rafa?,Wi?niewska, Aleksandra,Ponikiewski, ?ukasz,Caporali, Maria,Peruzzini, Maurizio,Pikies, Jerzy

, p. 1811 - 1817 (2014/04/17)

The reaction of R2P-P(SiMe3)Li (R = tBu, iPr) with the diimido molybdenum complex [(ArN)2MoCl2·dme] (Ar = 2,6-iPr2C6H3; dme = 1,2-dimethoxyethane) yielded the side-on-coordinated

Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes

Wi?niewska, Aleksandra,?apczuk-Krygier, Agnieszka,Baranowska, Katarzyna,Chojnacki, Jaros?aw,Matern, Eberhard,Pikies, Jerzy,Grubba, Rafa?

, p. 45 - 48 (2013/08/25)

The reactions of R2P-P(SiMe3)Li (R = tBu, iPr, iPr2N) with [Cp2MCl 2] (M = Zr, Hf), [Cp*z.ast;CpZrCl2] and [CpZrCl 3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R 2P-P(SiMe3)Li can act as a building block for the formation of the P2 ligand and the R2P-P(P2) and R2P-P(P2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P- P(P2) and R2P-P(P2)P-PR2 ligands were established by X-ray studies.

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